用于水净化的反渗透和纳滤膜综述
A Review on Reverse Osmosis and Nanofiltration Membranes for Water Purification.
作者信息
Yang Zi, Zhou Yi, Feng Zhiyuan, Rui Xiaobo, Zhang Tong, Zhang Zhien
机构信息
Department of Materials Science and Engineering, The Ohio State University, 2041 N. College Road, Columbus, OH 43210, USA.
State Key Laboratory of Precision Measurement Technology and Instrument, Tianjin University, Tianjin 300072, China.
出版信息
Polymers (Basel). 2019 Jul 29;11(8):1252. doi: 10.3390/polym11081252.
Sustainable and affordable supply of clean, safe, and adequate water is one of the most challenging issues facing the world. Membrane separation technology is one of the most cost-effective and widely applied technologies for water purification. Polymeric membranes such as cellulose-based (CA) membranes and thin-film composite (TFC) membranes have dominated the industry since 1980. Although further development of polymeric membranes for better performance is laborious, the research findings and sustained progress in inorganic membrane development have grown fast and solve some remaining problems. In addition to conventional ceramic metal oxide membranes, membranes prepared by graphene oxide (GO), carbon nanotubes (CNTs), and mixed matrix materials (MMMs) have attracted enormous attention due to their desirable properties such as tunable pore structure, excellent chemical, mechanical, and thermal tolerance, good salt rejection and/or high water permeability. This review provides insight into synthesis approaches and structural properties of recent reverse osmosis (RO) and nanofiltration (NF) membranes which are used to retain dissolved species such as heavy metals, electrolytes, and inorganic salts in various aqueous solutions. A specific focus has been placed on introducing and comparing water purification performance of different classes of polymeric and ceramic membranes in related water treatment industries. Furthermore, the development challenges and research opportunities of organic and inorganic membranes are discussed and the further perspectives are analyzed.
可持续且价格合理地供应清洁、安全和充足的水是世界面临的最具挑战性的问题之一。膜分离技术是水净化领域最具成本效益且应用广泛的技术之一。自1980年以来,诸如纤维素基(CA)膜和复合薄膜(TFC)膜等聚合物膜一直主导着该行业。尽管进一步开发性能更优的聚合物膜很费力,但无机膜开发方面的研究成果和持续进展发展迅速,并解决了一些遗留问题。除了传统的陶瓷金属氧化物膜外,由氧化石墨烯(GO)、碳纳米管(CNTs)和混合基质材料(MMMs)制备的膜因其具有可调孔结构、优异的化学、机械和热耐受性、良好的脱盐性能和/或高水渗透性等理想特性而备受关注。本综述深入探讨了用于截留各种水溶液中重金属、电解质和无机盐等溶解物质的反渗透(RO)和纳滤(NF)膜的合成方法和结构特性。特别着重介绍和比较了相关水处理行业中不同类型聚合物膜和陶瓷膜的水净化性能。此外,还讨论了有机膜和无机膜的发展挑战与研究机遇,并分析了未来的发展前景。