Pelton Matthew, Storm S David, Leng Haixu
Department of Physics, UMBC (University of Maryland, Baltimore County), 1000 Hilltop Circle, Baltimore, MD 21250, USA.
Nanoscale. 2019 Aug 8;11(31):14540-14552. doi: 10.1039/c9nr05044b.
Strong coupling between plasmons in metal nanoparticles and single excitons in molecules or semiconductor nanomaterials has recently attracted considerable experimental effort for potential applications in quantum-mechanical and classical optical information processing and for fundamental studies of light-matter interaction. Here, we review the theory behind strong plasmon-exciton coupling and provide analytical expressions that can be used for fitting experimental data, particularly the commonly measured scattering spectra. We re-analyze published data using these expressions, providing a uniform method for evaluating and quantifying claims of strong coupling that avoids ambiguities in distinguishing between Rabi splitting and exciton-induced transparency (or Fano-like interference between plasmons and excitons).
金属纳米颗粒中的等离激元与分子或半导体纳米材料中的单个激子之间的强耦合,最近吸引了大量实验研究,其潜在应用包括量子力学和经典光学信息处理,以及光与物质相互作用的基础研究。在此,我们回顾强等离激元 - 激子耦合背后的理论,并提供可用于拟合实验数据的解析表达式,特别是常用的散射光谱。我们使用这些表达式重新分析已发表的数据,提供一种统一的方法来评估和量化强耦合的相关论断,避免在区分拉比分裂和激子诱导透明(或等离激元和激子之间类似法诺的干涉)时产生歧义。