Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414006, China.
Org Biomol Chem. 2019 Aug 28;17(34):7918-7926. doi: 10.1039/c9ob01321k.
An efficient method for visible-light-mediated sulfonylation/arylation of the C-C σ-bond in vinylcyclopropanes with sulfonyl chlorides to synthesize 1-sulfonylmethyl-substituted 3,4-dihydronaphalenes has been developed. A radical-type pathway has been proved in this transformation. This difunctionalization procedure shows a series of advantages, such as the use of commercially and easily available sulfonyl chlorides, mild conditions, and eco-friendly energy.
一种高效的可见光介导方法，用于将乙烯基环丙烷中的 C-C σ 键与磺酰氯进行磺酰化/芳基化反应，以合成 1-磺酰甲基取代的 3,4-二氢萘。在这种转化中已经证明了自由基型途径。该双官能化程序具有一系列优点，例如使用商业上和容易获得的磺酰氯、温和的条件和环保的能源。
