Wang Xiu, Wang Zhenhua, Nishihara Yasushi
Graduate School of Natural Science and Technology, Okayama University 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530, Japan.
Chem Commun (Camb). 2019 Aug 29;55(71):10507-10510. doi: 10.1039/c9cc05325e.
Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.
已开发出镍/铜共催化的酰氟与硅硼烷的脱羰硅基化反应，通过碳-氟键断裂和碳-硅键形成，高效且具有良好的官能团兼容性地制备各种芳基硅烷。这种转化不仅可以扩展酰氟的官能化类型，还能补充芳基硅烷的合成路线。
