Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-Ku, Kyoto 606-8502, Japan.
J Chem Phys. 2019 Sep 7;151(9):090901. doi: 10.1063/1.5098402.
Chemical reaction dynamics in liquids and at interfaces are central themes in the materials, energy, and environmental sciences. Ultrafast photoelectron spectroscopy of liquids enables unprecedented access to the electronic dynamics of transient chemical species, providing deeper insights into nonadiabatic reaction dynamics in aqueous solutions, which are strongly coupled with solvation dynamics.
液体和界面中的化学反应动力学是材料、能源和环境科学的核心主题。液体的超快光电子能谱使得人们能够以前所未有的方式了解瞬态化学物种的电子动力学,从而深入了解与溶剂化动力学强烈耦合的水溶液中非绝热反应动力学。