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酰胺基功能化纤维素基吸附剂从水溶液中去除重金属离子和阴离子染料。

Removal of heavy metal ions and anionic dyes from aqueous solutions using amide-functionalized cellulose-based adsorbents.

机构信息

Department of Pharmaceutical Analysis, China Pharmaceutical University, China.

Institute of Agricultural Facilities and Equipment, Jiangsu Academy of Agricultural Sciences, China; Key Laboratory for Protected Agricultural Engineering in the Middle and Lower Reaches of Yangtze River, Ministry of Agriculture, China.

出版信息

Carbohydr Polym. 2020 Feb 15;230:115619. doi: 10.1016/j.carbpol.2019.115619. Epub 2019 Nov 14.

DOI:10.1016/j.carbpol.2019.115619
PMID:31887868
Abstract

An efficient, ecofriendly, amide-functionalized cellulose-based porous adsorbent was synthesized by a cross-linking reaction between cellulose filament fibers and bisacrylamide at room temperature. This process is simple, fast and inexpensive, and has significant potential for industrial applications. The prepared material has numerous adsorption sites, resulting in the highly efficient removal of anionic dyes and copper ions from aqueous media. The maximum adsorption capacities of this cellulose-based adsorbent for the dyes Acid Black 1 and Acid Red 18 and for copper ions were 751.8, 417.9, and 51.3 mg g, respectively. Regeneration experiments showed that the removal efficiencies for all model pollutants remained above 92 % after five consecutive recycling trials. These results indicate that amide-functionalized cellulose-based adsorbents could possibly be used to treat industrial wastewaters.

摘要

一种高效、环保的酰胺功能化纤维素基多孔吸附剂,通过纤维素长丝纤维与双丙烯酰胺在室温下的交联反应合成。该过程简单、快速且成本低廉,具有重要的工业应用潜力。所制备的材料具有众多吸附位点,能够高效去除水相中阴离子染料和铜离子。该纤维素基吸附剂对酸性黑 1 和酸性红 18 染料以及铜离子的最大吸附容量分别为 751.8、417.9 和 51.3 mg/g。再生实验表明,在连续五次循环试验后,所有模型污染物的去除效率均保持在 92%以上。这些结果表明,酰胺功能化纤维素基吸附剂可用于处理工业废水。

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