Department of Chemistry, University College London, 20 Gordon Street, London, WC1E 0AJ, UK.
Department of Chemical Engineering, University College London, Torrington Place, WC1E 7JE, UK.
J Mater Chem B. 2019 May 22;7(20):3310-3318. doi: 10.1039/c9tb00440h.
We report here for the first time how the combination of a precursor solution and low temperature (170 °C) aerosol assisted chemical vapour deposition were used to bond a copper coating to ultra-high molecular weight polyethylene (UHMWPE) and promote robustness. This metallic thin film remained intact on the UHMWPE substrate after the Scotch tape test and showed notable wear-resistance after 10 cycles of sand paper-abrasion. Antimicrobial assays against both Escherichia coli and Staphylococcus aureus revealed potent dark bactericidal activity with 99.999% reduction in bacterial number within 15 minutes. These results suggest that the modified UHMWPE could be a potential candidate for antimicrobial plastics and in the long term may find application in prosthetic joint applications.
我们首次报告了如何通过前驱溶液和低温(170°C)气溶胶辅助化学气相沉积相结合,将铜涂层粘结到超高分子量聚乙烯(UHMWPE)上并提高其稳定性。经过 Scotch 胶带测试后,这种金属薄膜仍然完好无损地附着在 UHMWPE 基底上,并且在经过 10 次砂纸磨损循环后表现出显著的耐磨性。针对大肠杆菌和金黄色葡萄球菌的抗菌试验表明,这种材料具有很强的暗杀菌活性,在 15 分钟内可将细菌数量减少 99.999%。这些结果表明,改性 UHMWPE 可能成为抗菌塑料的潜在候选材料,从长远来看,它可能在假肢关节应用中得到应用。