Carlos Emanuel, Martins Rodrigo, Fortunato Elvira, Branquinho Rita
Materials Science Department, CENIMAT/i3N, Faculdade de Ciências e Tecnologia (FCT), Universidade NOVA de Lisboa (UNL) and CEMOP/UNINOVA, 2829-516, Caparica, Portugal.
Chemistry. 2020 Jul 27;26(42):9099-9125. doi: 10.1002/chem.202000678. Epub 2020 Apr 21.
Solution combustion synthesis (SCS) has been widely used to produce simple and complex oxides with a desired morphology (size and shape). SCS is valuable due to low cost, simplicity and energy efficient synthesis. To guarantee the best molecular-level mixing of reactants in an aqueous or solvent-based solution some parameters need to be controlled, such as fuel type, metal cations precursors, stoichiometry ratio (φ), pH effect, atmosphere and initiation type. These determine the final properties of the oxide materials, providing the potential to reach different morphologies, which are essential for their final applications. This Review article focuses on the crucial parameters in SCS and how these affect the overall materials properties from nanostructures to thin films. To finalize, special attention is given to the application of SCS to form metal oxide thin films at low temperature and their application in thin film transistors (TFTs).
溶液燃烧合成法(SCS)已被广泛用于制备具有所需形貌(尺寸和形状)的简单和复杂氧化物。由于成本低、合成简单且节能,SCS具有重要价值。为确保反应物在水性或溶剂基溶液中实现最佳的分子水平混合,需要控制一些参数,如燃料类型、金属阳离子前驱体、化学计量比(φ)、pH值影响、气氛和引发类型。这些参数决定了氧化物材料的最终性能,为获得不同形貌提供了可能性,而这些形貌对于其最终应用至关重要。这篇综述文章重点关注SCS中的关键参数,以及这些参数如何影响从纳米结构到薄膜的整体材料性能。最后,特别关注SCS在低温下形成金属氧化物薄膜的应用及其在薄膜晶体管(TFT)中的应用。