Januszewicz Katarzyna, Kazimierski Paweł, Kosakowski Wojciech, Lewandowski Witold M
Department of Energy Conversion and Storage, Faculty of Chemistry, Gdańsk University of Technology, G. Narutowicza 11/12, PL-80-233 Gdańsk, Poland.
Institute of Fluid-Flow Machinery, Polish Academy of Sciences, Fiszera 14 st., PL-80-231 Gdańsk, Poland.
Materials (Basel). 2020 Mar 17;13(6):1359. doi: 10.3390/ma13061359.
This review deals with the technologies of limonene production from waste tyre pyrolysis. Thermal decomposition is attractive for tackling the waste tyre disposal problem, as it enables both: energy to be recovered and limonene to be obtained. This material management recycling of tyres is environmentally more beneficial than the burning of all valuable products, including limonene. Given this recoverability of materials from waste tyres, a comprehensive evaluation was carried out to show the main effect of process conditions (heating rate, temperature, pressure, carrier gas flow rate, and type of volatile residence and process times) for different pyrolytic methods and types of apparatus on the yield of limonene. All the results cited are given in the context of the pyrolysis method and the type of reactor, as well as the experimental conditions in order to avoid contradictions between different researchers. It is shown that secondary and side reactions are very sensitive to interaction with the above-mentioned variables. The yields of all pyrolytic products are also given, as background for limonene, the main product reported in this study.
本综述涉及从废轮胎热解中生产柠檬烯的技术。热分解对于解决废轮胎处置问题具有吸引力,因为它既能回收能量,又能获得柠檬烯。这种轮胎的材料管理回收在环境方面比燃烧包括柠檬烯在内的所有有价值产品更有益。鉴于从废轮胎中回收材料的可能性,进行了全面评估,以展示不同热解方法和设备类型的工艺条件(加热速率、温度、压力、载气流量、挥发性物质停留类型和工艺时间)对柠檬烯产量的主要影响。引用的所有结果都是在热解方法、反应器类型以及实验条件的背景下给出的,以避免不同研究人员之间的矛盾。结果表明,二次反应和副反应对与上述变量的相互作用非常敏感。还给出了所有热解产物的产量,作为本研究报告的主要产物柠檬烯的背景信息。