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用于独特物理化学应用的氧化石墨烯-银(GO-Ag)纳米复合材料的新型合成方法。

A Novel Synthesis of the Graphene Oxide-Silver (GO-Ag) Nanocomposite for Unique Physiochemical Applications.

作者信息

Kumari Sujata, Sharma Pratibha, Yadav Sunny, Kumar Jitender, Vij Ankush, Rawat Pooja, Kumar Shalendra, Sinha Chittaranjan, Bhattacharya Jaydeep, Srivastava Chandra Mohan, Majumder Sudip

机构信息

Department of Chemistry, Amity School of Applied Sciences, Amity University Haryana, Gurgaon 122413, India.

Nanophosphors Lab, Department of Physics, Amity School of Applied Sciences, Amity University Haryana, Gurgaon 122412, India.

出版信息

ACS Omega. 2020 Mar 6;5(10):5041-5047. doi: 10.1021/acsomega.9b03976. eCollection 2020 Mar 17.

DOI:10.1021/acsomega.9b03976
PMID:32201790
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7081393/
Abstract

Graphene oxide-silver nanocomposite (GO-Ag) was fabricated via the sonochemical method, which shows unique physiochemical properties. Graphene oxide (GO) and silver nanoparticles (AgNPs) were synthesized by modified Hummer's and Chemical reduction methods, respectively. The synthesized nanocomposite was characterized using powder X-ray diffraction, Raman spectroscopy, and Fourier-transform infrared spectroscopy. The surface morphology of synthesized nanoparticles was studied using scanning electron microscopy and transmission electron microscopy. The thermoluminescence property of the nanocomposite was analyzed by irradiating the samples in gamma radiation at 1 kGy. Electrochemical reversibility of the GO-Ag nanocomposite was examined by cyclic voltammetry. The photocatalytic application of the nanocomposite was studied using degradation of methylene blue dye. Results reveal that doping of AgNPs on the GO surface not only improves its dye degradation property but also enhances its thermoluminescence property. This knowledge will be helpful in determining the antibacterial property of the GO-Ag nanocomposite in the future.

摘要

通过声化学方法制备了氧化石墨烯-银纳米复合材料(GO-Ag),其具有独特的物理化学性质。氧化石墨烯(GO)和银纳米颗粒(AgNPs)分别通过改进的Hummer法和化学还原法合成。使用粉末X射线衍射、拉曼光谱和傅里叶变换红外光谱对合成的纳米复合材料进行了表征。利用扫描电子显微镜和透射电子显微镜研究了合成纳米颗粒的表面形态。通过在1 kGy的γ辐射下照射样品来分析纳米复合材料的热发光性能。通过循环伏安法研究了GO-Ag纳米复合材料的电化学可逆性。利用亚甲基蓝染料的降解研究了纳米复合材料的光催化应用。结果表明,在GO表面掺杂AgNPs不仅提高了其染料降解性能,还增强了其热发光性能。这一知识将有助于未来确定GO-Ag纳米复合材料的抗菌性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c877/7081393/46bed9e357f6/ao9b03976_0010.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c877/7081393/c70dff6ebdc1/ao9b03976_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c877/7081393/f1a1c68cf99b/ao9b03976_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c877/7081393/879c7c31adfa/ao9b03976_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c877/7081393/a67d2e567150/ao9b03976_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c877/7081393/2ecb59c72a31/ao9b03976_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c877/7081393/d75d61e71bef/ao9b03976_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c877/7081393/e2d296bed9f1/ao9b03976_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c877/7081393/cabf9cd2ed75/ao9b03976_0008.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c877/7081393/46bed9e357f6/ao9b03976_0010.jpg

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