铁催化的四芳基萘啶的合成、结构和光物理性质。
Iron-Catalyzed Synthesis, Structure, and Photophysical Properties of Tetraarylnaphthidines.
机构信息
Faculty of Chemistry, Technische Universität Dresden, Bergstraße 66, 01069 Dresden, Germany.
A. E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia.
出版信息
Molecules. 2020 Apr 1;25(7):1608. doi: 10.3390/molecules25071608.
We describe the synthesis and photophysical properties of tetraarylnaphthidines. Our synthetic approach is based on an iron-catalyzed oxidative C-C coupling reaction as the key step using a hexadecafluorinated iron-phthalocyanine complex as a catalyst and air as the sole oxidant. The ,,','-tetraarylnaphthidines proved to be highly fluorescent with quantum yields of up to 68%.
我们描述了四芳基萘啶的合成及光物理性质。我们的合成方法基于铁催化的氧化 C-C 偶联反应，该反应是使用十六氟铁酞菁络合物作为催化剂和空气作为唯一氧化剂的关键步骤。所得到的,,,',-四芳基萘啶具有高达 68%的量子产率，表现出很强的荧光性。
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