碘催化以1-芳基三氮烯/CS组合作为新型亚磺酰化源合成3-芳硫基吲哚
Iodine-Catalyzed Synthesis of 3-Arylthioindoles Employing a 1-Aryltriazene/CS Combination as a New Sulfenylation Source.
作者信息
Pandey Anand Kumar, Chand Shiv, Singh Rahul, Kumar Saurabh, Singh Krishna Nand
机构信息
Department of Chemistry, Centre of Advanced Study, Institute of Science, Banaras Hindu University, Varanasi 221005, India.
出版信息
ACS Omega. 2020 Mar 24;5(13):7627-7635. doi: 10.1021/acsomega.0c00472. eCollection 2020 Apr 7.
Abstract
A practical approach for the regioselective synthesis of 3-arylthioindoles has been accomplished using a combination of 1-aryltriazene/CS as a new sulfenylation source. The methodology employs molecular iodine as a catalyst and is compatible with a variety of structurally diverse reactants.
摘要
使用1-芳基三氮烯/CS作为一种新的硫代化源，已实现了一种区域选择性合成3-芳硫基吲哚的实用方法。该方法采用分子碘作为催化剂，并且与各种结构多样的反应物兼容。
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