Zhang Youcan, Yin Zhiping, Wang Hai, Wu Xiao-Feng
Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany.
Chem Commun (Camb). 2020 Jun 25;56(51):7045-7048. doi: 10.1039/d0cc02784g.
Herein, a new method of iron-catalyzed carbonylative cyclization of γ,δ-unsaturated aromatic oxime esters to functionalized pyrrolines has been developed. By using readily available substrates, 32 examples of functionalized pyrrolines were prepared in moderate to good yields. Notably, examples of reduction and cycloaddition reactions of the obtained product were given as well.
在此，已开发出一种铁催化γ,δ-不饱和芳族肟酯羰基化环化制备官能化吡咯啉的新方法。通过使用易于获得的底物，以中等至良好的产率制备了32个官能化吡咯啉的实例。值得注意的是，还给出了所得产物的还原和环加成反应的实例。
