Sun Yiming, Song Cheng, Yin Siqi, Qiao Leilei, Wan Qin, Liu Jialu, Wang Rui, Zeng Fei, Pan Feng
Key Laboratory of Advanced Materials (MOE), School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China.
ACS Appl Mater Interfaces. 2020 Jul 1;12(26):29481-29486. doi: 10.1021/acsami.0c07238. Epub 2020 Jun 17.
Conductive bridge random access memory (CBRAM) is one of the most representative emerging nonvolatile memories in virtue of its excellent performance on speed, high-density integration, and power efficiency. Resistive switching behaviors in CBRAM involving the formation/rupture of metallic conductive filaments are dominated by cation migration and redox processes. It is all in the pursuit to decrease the operation current for low-power consumption and to enhance the current compliance-dependent reliability. Here, we propose a novel structure of Pt/TaO:Ag/TaO/Pt with nonvolatile switching at ∼1 μA and achieve a five-resistance-state multilevel cell operation under different compliance currents. Different from the nanocone-shaped filaments reported in traditional Ag top electrode devices, cluster-type filaments were captured in our memory devices, explaining the low-operation current-resistive switching behaviors. Meanwhile, Cu-doped counterpart devices also display similar operations. Such memory devices are more inclined to achieve low-power consumption and offer feasibility to large-scale memory crossbar integration.
导电桥随机存取存储器(CBRAM)凭借其在速度、高密度集成和功率效率方面的出色表现,成为最具代表性的新兴非易失性存储器之一。CBRAM中涉及金属导电细丝形成/断裂的电阻开关行为受阳离子迁移和氧化还原过程主导。其目的在于降低工作电流以实现低功耗,并提高电流依从性相关的可靠性。在此,我们提出一种新型结构Pt/TaO:Ag/TaO/Pt,其在约1 μA时具有非易失性开关特性,并在不同依从电流下实现了五电阻态多级单元操作。与传统银顶电极器件中报道的纳米锥形细丝不同,我们的存储器件中捕获到了簇状细丝,这解释了低工作电流电阻开关行为。同时,铜掺杂的对应器件也表现出类似的操作。此类存储器件更倾向于实现低功耗,并为大规模存储器交叉点集成提供了可行性。