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不同婴幼儿食品中高氯酸盐、氯酸盐和极性除草剂的出现情况。

Occurrence of perchlorate, chlorate and polar herbicides in different baby food commodities.

机构信息

Department of Health, Animal Science and Food Safety, University of Milan, Via Celoria 10, 20133 Milan, Italy.

Istituto Zooprofilattico Sperimentale del Piemonte, Liguria e Valle d'Aosta, Via Bologna 148, 10154 Turin, Italy.

出版信息

Food Chem. 2020 Nov 15;330:127205. doi: 10.1016/j.foodchem.2020.127205. Epub 2020 Jun 4.

Abstract

The incidence of endocrine disruptors, both possible (glyphosate and glufosinate), and demonstrated (perchlorate and chlorate), was estimated in baby food commodities (meat, fish, cheese, vegetable and fruit). Ion-chromatography coupled to high resolution mass spectrometry analysis of the 105 samples did not show traces of glyphosate, glufosinate or their metabolites, while in 10.5% of the samples a quantifiable amount of perchlorate was found. Some samples based on fruit and vegetables revealed a substantial amount of chlorate, especially the preparations that contained carrots and potatoes: five samples were in a concentration range of 40-120 μg kg, while one homogenized pear sample reached 372.2 μg kg. The pure meat samples revealed occasional chlorate appearance, with less than 10 μg kg. This is the first report of chlorate evaluated in various types of baby food and may serve as symptomatic data regarding its occurrence in infant/toddler diets. Therefore, effective monitoring programs and subsequent strict regulations are strongly required.

摘要

婴儿食品(肉、鱼、奶酪、蔬菜和水果)中内分沁干扰物(可能的草甘膦和草铵膦,以及已证实的高氯酸盐和氯酸盐)的发生率进行了估计。对 105 个样本进行的离子色谱-高分辨率质谱联用分析并未显示草甘膦、草铵膦或其代谢物的痕迹,但在 10.5%的样本中发现了可量化的高氯酸盐。一些基于水果和蔬菜的样本显示出大量的氯酸盐,特别是含有胡萝卜和土豆的制剂:五个样本的浓度范围在 40-120μg/kg 之间,而一个均质化的梨样本达到 372.2μg/kg。纯肉样本偶尔会出现氯酸盐,含量低于 10μg/kg。这是首次在各种类型的婴儿食品中评估氯酸盐的报告,可能是关于其在婴儿/幼儿饮食中存在的症状数据。因此,强烈需要制定有效的监测计划和后续的严格法规。

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