Direct and indirect Z-scheme heterostructure-coupled photosystem enabling cooperation of CO reduction and HO oxidation.

The stoichiometric photocatalytic reaction of CO with HO is one of the great challenges in photocatalysis. Here, we construct a CuO-Pt/SiC/IrO composite by a controlled photodeposition and then an artificial photosynthetic system with Nafion membrane as diaphragm separating reduction and oxidation half-reactions. The artificial system exhibits excellent photocatalytic performance for CO reduction to HCOOH and HO oxidation to O under visible light irradiation. The yields of HCOOH and O meet almost stoichiometric ratio and are as high as 896.7 and 440.7 μmol g h, respectively. The high efficiencies of CO reduction and HO oxidation in the artificial system are attributed to both the direct Z-scheme electronic structure of CuO-Pt/SiC/IrO and the indirect Z-scheme spatially separated reduction and oxidation units, which greatly prolong lifetime of photogenerated electrons and holes and prevent the backward reaction of products. This work provides an effective and feasible strategy to increase the efficiency of artificial photosynthesis.