在纯反应介质中过氧酶催化苯乙烯衍生物的环氧化反应
Peroxygenase-Catalysed Epoxidation of Styrene Derivatives in Neat Reaction Media.
作者信息
Rauch Marine C R, Tieves Florian, Paul Caroline E, Arends Isabel W C E, Alcalde Miguel, Hollmann Frank
机构信息
Department of Biotechnology Delft University of Technology Delft 2629HZ The Netherlands.
Faculty of Science Utrecht University Utrecht 3584CD The Netherlands.
出版信息
ChemCatChem. 2019 Sep 19;11(18):4519-4523. doi: 10.1002/cctc.201901142. Epub 2019 Aug 27.
Abstract
Biocatalytic oxyfunctionalisation reactions are traditionally conducted in aqueous media limiting their production yield. Here we report the application of a peroxygenase in neat reaction conditions reaching product concentrations of up to 360 mM.
摘要
传统上，生物催化氧官能化反应在水性介质中进行，这限制了它们的产率。在此，我们报道了一种过氧合酶在纯反应条件下的应用，其产物浓度高达360 mM。
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