Qin Yi, Liu Xi, Jia Pei-Pei, Xu Lin, Yang Hai-Bo
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, 3663 N. Zhongshan Road, Shanghai 200241, China.
Chem Soc Rev. 2020 Jul 9. doi: 10.1039/c9cs00797k.
During the past few years, the construction of BODIPY-based macrocycles has attracted extensive interest due to the widespread applications of these materials in sensing, bioimaging, molecular machines, and photodynamic therapy (PDT). Since significant progress has been made in this field, it is time to summarize the recent developments involving BODIPY-based macrocycles. In this review, we will briefly introduce the synthesis routes of BODIPY-based macrocycles, including a covalent synthetic protocol and a noncovalent self-assembly protocol. In addition, we will discuss the photophysical and photochemical properties and the applications of these BODIPY-based macrocycles in the areas of sensing, bioimaging, photodynamic therapy, etc.
在过去几年中,基于BODIPY的大环化合物的构建引起了广泛关注,因为这些材料在传感、生物成像、分子机器和光动力疗法(PDT)中有着广泛的应用。由于该领域已取得显著进展,现在是时候总结基于BODIPY的大环化合物的最新进展了。在这篇综述中,我们将简要介绍基于BODIPY的大环化合物的合成路线,包括共价合成方案和非共价自组装方案。此外,我们将讨论这些基于BODIPY的大环化合物的光物理和光化学性质以及它们在传感、生物成像、光动力疗法等领域的应用。