非均相介质中的RAFT介导聚合反应。

RAFT mediated polymerisation in heterogeneous media.

作者信息

McLeary J B, Klumperman B

机构信息

UNESCO Centre for Macromolecules and Materials, Department of Chemistry and Polymer Science, University of Stellenbosch, Private Bag X1, Matieland 7602, South Africa.

UNESCO Centre for Macromolecules and Materials, Department of Chemistry and Polymer Science, University of Stellenbosch, Private Bag X1, Matieland 7602, South Africa and Laboratory of Polymer Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.

出版信息

Soft Matter. 2006 Dec 12;2(1):45-53. doi: 10.1039/b513575c.

DOI:10.1039/b513575c

PMID:32646092

Abstract

Reversible addition fragmentation chain transfer (RAFT) mediated polymerisation is one of a number of living radical polymerisation processes that were developed over the last decade. The RAFT process is facilitating the synthesis of controlled macromolecular architectures radical polymerisation in homogeneous and heterogeneous media. Here we discuss the progress in the use of the RAFT process, the past, the state of the art and potential directions for the future with specific emphasis on heterogeneous reactions.

摘要

可逆加成-断裂链转移（RAFT）介导的聚合反应是过去十年中开发的多种活性自由基聚合方法之一。RAFT方法促进了在均相和非均相介质中合成具有可控大分子结构的自由基聚合反应。在此，我们讨论RAFT方法的应用进展，包括过去、当前的技术水平以及未来的潜在发展方向，特别强调非均相反应。