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通向领先的潜在“将杀”之着：有机金属卤化物钙钛矿中的铋，结构、性质及应用

A Potential Checkmate to Lead: Bismuth in Organometal Halide Perovskites, Structure, Properties, and Applications.

作者信息

Attique Sanam, Ali Nasir, Ali Shahid, Khatoon Rabia, Li Na, Khesro Amir, Rauf Sajid, Yang Shikuan, Wu Huizhen

机构信息

Institute for Composites Science and Innovation (InCSI) School of Material Science and Engineering Zhejiang University Hangzhou 310027 P. R. China.

Zhejiang Province Key Laboratory of Quantum Technology and Devices and Department of Physics State Key Laboratory for Silicon Materials Zhejiang University Hangzhou 310027 P. R. China.

出版信息

Adv Sci (Weinh). 2020 May 27;7(13):1903143. doi: 10.1002/advs.201903143. eCollection 2020 Jul.

DOI:10.1002/advs.201903143
PMID:32670745
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7341095/
Abstract

The remarkable optoelectronic properties and considerable performance of the organo lead-halide perovskites (PVKs) in various optoelectronic applications grasp tremendous scientific attention. However, the existence of the toxic lead in these compounds is threatening human health and remains a major concern in the way of their commercialization. To address this issue, numerous nontoxic alternatives have been reported. Among these alternatives, bismuth-based PVKs have emerged as a promising substitute because of similar optoelectronic properties and extended environmental stability. This work communicates briefly about the possible lead-alternatives and explores bismuth-based perovskites comprehensively, in terms of their structures, optoelectronic properties, and applications. A brief description of lead-toxification is provided and the possible Pb-alternatives from the periodic table are scrutinized. Then, the classification and crystal structures of various Bi-based perovskites are elaborated on. Detailed optoelectronic properties of Bi-based perovskites are also described and their optoelectronic applications are abridged. The overall photovoltaic applications along with device characteristics (i.e., , , fill factor, FF, and power conversion efficiency, PCE), fabrication method, device architecture, and operational stability are also summarized. Finally, a conclusion is drawn where a brief outlook highlights the challenges that hamper the future progress of Bi-based optoelectronic devices and suggestions for future directions are provided.

摘要

有机铅卤化物钙钛矿（PVK）在各种光电器件应用中卓越的光电性能和出色的表现引起了科学界的广泛关注。然而，这些化合物中有毒铅的存在威胁着人类健康，并且仍然是其商业化进程中的主要问题。为了解决这个问题，人们已经报道了许多无毒替代品。在这些替代品中，铋基PVK因其相似的光电性能和更高的环境稳定性而成为一种有前途的替代物。本文简要介绍了可能的铅替代品，并从结构、光电性能和应用等方面全面探讨了铋基钙钛矿。文中提供了铅中毒的简要描述，并仔细研究了元素周期表中可能的铅替代品。然后，阐述了各种铋基钙钛矿的分类和晶体结构。还描述了铋基钙钛矿的详细光电性能，并简述了它们的光电应用。文中还总结了整体光伏应用以及器件特性（即开路电压、短路电流、填充因子、FF和功率转换效率、PCE）、制造方法、器件结构和运行稳定性。最后得出结论，简要展望突出了阻碍铋基光电器件未来发展的挑战，并提供了未来发展方向的建议。

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