Saggau Christian N, Gabler Felix, Karnaushenko Dmitriy D, Karnaushenko Daniil, Ma Libo, Schmidt Oliver G
Institute for Integrative Nanosciences, Leibniz IFW Dresden, Helmholtzstraße 20, Dresden, 01069, Germany.
Material Systems for Nanoelectronics, Chemnitz University of Technology, Str. der Nationen 62, Chemnitz, 09111, Germany.
Adv Mater. 2020 Sep;32(37):e2003252. doi: 10.1002/adma.202003252. Epub 2020 Jul 19.
Mechanical strain formed at the interfaces of thin films has been widely applied to self-assemble 3D microarchitectures. Among them, rolled-up microtubes possess a unique 3D geometry beneficial for working as photonic, electromagnetic, energy storage, and sensing devices. However, the yield and quality of microtubular architectures are often limited by the wet-release of lithographically patterned stacks of thin-film structures. To address the drawbacks of conventionally used wet-etching methods in self-assembly techniques, here a dry-release approach is developed to roll-up both metallic and dielectric, as well as metallic/dielectric hybrid thin films for the fabrication of electronic and optical devices. A silicon thin film sacrificial layer on insulator is etched by dry fluorine chemistry, triggering self-assembly of prestrained nanomembranes in a well-controlled wafer scale fashion. More than 6000 integrated microcapacitors as well as hundreds of active microtubular optical cavities are obtained in a simultaneous self-assembly process. The fabrication of wafer-scale self-assembled microdevices results in high yield, reproducibility, uniformity, and performance, which promise broad applications in microelectronics, photonics, and opto-electronics.
薄膜界面处形成的机械应变已被广泛应用于自组装三维微结构。其中,卷绕微管具有独特的三维几何形状,有利于用作光子、电磁、能量存储和传感设备。然而,微管结构的产量和质量常常受到光刻图案化薄膜结构堆叠湿法释放的限制。为了解决自组装技术中传统湿法蚀刻方法的缺点,本文开发了一种干法释放方法,用于卷绕金属和介电薄膜以及金属/介电混合薄膜,以制造电子和光学器件。通过干法氟化学蚀刻绝缘体上的硅薄膜牺牲层,以良好控制的晶圆规模方式触发预应变纳米膜的自组装。在同时进行的自组装过程中获得了6000多个集成微电容器以及数百个有源微管光学腔。晶圆级自组装微器件的制造具有高产率、可重复性、均匀性和性能,有望在微电子、光子学和光电子学中得到广泛应用。