Simon Patrice, Gogotsi Yury
Materials Science Department-CIRIMAT, Université Paul Sabatier, Toulouse, France.
Réseau sur le Stockage Electrochimique de l'Energie (RS2E), FR CNRS, Toulouse, France.
Nat Mater. 2020 Nov;19(11):1151-1163. doi: 10.1038/s41563-020-0747-z. Epub 2020 Aug 3.
Electrochemical capacitors can store electrical energy harvested from intermittent sources and deliver energy quickly, but their energy density must be increased if they are to efficiently power flexible and wearable electronics, as well as larger equipment. This Review summarizes progress in the field of materials for electrochemical capacitors over the past decade as well as outlines key perspectives for future research. We describe electrical double-layer capacitors based on high-surface-area carbons, pseudocapacitive materials such as oxides and the two-dimensional inorganic compounds known as MXenes, and emerging microdevices for the Internet of Things. We show that new nanostructured electrode materials and matching electrolytes are required to maximize the amount of energy and speed of delivery, and different manufacturing methods will be needed to meet the requirements of the future generation of electronic devices. Scientifically justified metrics for testing, comparison and optimization of various kinds of electrochemical capacitors are provided and explained.
电化学电容器能够存储从间歇性电源收集的电能并快速释放能量,但要高效地为柔性和可穿戴电子产品以及更大的设备供电,就必须提高其能量密度。本综述总结了过去十年电化学电容器材料领域的进展,并概述了未来研究的关键观点。我们描述了基于高表面积碳的双电层电容器、诸如氧化物等赝电容材料以及被称为MXenes的二维无机化合物,还有用于物联网的新兴微型设备。我们表明,需要新型纳米结构电极材料和匹配的电解质来最大化能量存储量和释放速度,并且需要不同的制造方法来满足下一代电子设备的要求。文中提供并解释了用于测试、比较和优化各类电化学电容器的科学合理的指标。