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压缩性公式及其在空气、稀有气体、一些碳氢化合物气体、一些双原子简单气体和其他一些流体中的应用。

Formula of compressibility and using it for air, noble gases, some hydrocarbons gases, some diatomic simple gases and some other fluids.

作者信息

Al-Raeei Marwan, El-Daher Moustafa Sayem

机构信息

Faculty of Sciences, Damascus University, Damascus, Syrian Arab Republic.

Faculty of Informatics and Communications, Arab International University, Daraa, Syrian Arab Republic.

出版信息

BMC Chem. 2020 Aug 9;14(1):47. doi: 10.1186/s13065-020-00702-5. eCollection 2020 Dec.

Abstract

Based on solutions of the Ornstein-Zernike equation (OZE) of Lennard-Jones potential for mean spherical approximation (MSA), we derive analytical formula for the compressibility assuming that the system is of low density, homogeneous, isotropic and composed of one component. Depending on this formula, we find the values of the bulk modulus and the compressibility of air at room temperature and the bulk modulus and the compressibility of Methane, Ethylene, Propylene and Propane at nine per ten of critical temperature of each hydrocarbon. Also, we find the speed of sound in the air at various temperatures, the speed of sound in each of Helium, Neon, Argon, Krypton, Xenon, Methane, Ethylene, Propylene, Propane, Hydrogen, Nitrogen, Fluorine, Chlorine, Oxygen, Nitrous oxide (laughing gas), Carbon dioxide, Nitric oxide, Carbon monoxide, Sulphur dioxide and dichlorodifluoromethane at room temperature. Besides, we find the speed of sound in Methane, Ethylene, Propylene and Propane at nine per ten of critical temperature of each hydrocarbons depending on the formula we find. We show that the simple formula we derive in this work is reliable and agrees with the results obtained from other studies and literatures. We believe it can be used for many systems which are in low densities and described by Lennard-Jones potential.

摘要

基于针对平均球近似(MSA)的 Lennard-Jones 势的 Ornstein-Zernike 方程(OZE)的解,我们推导了压缩率的解析公式,假设系统为低密度、均匀、各向同性且由单一组分组成。根据此公式,我们求出了室温下空气的体积模量和压缩率,以及每种碳氢化合物在其临界温度的十分之九时甲烷、乙烯、丙烯和丙烷的体积模量和压缩率。此外,我们求出了不同温度下空气中的声速,以及室温下氦气、氖气、氩气、氪气、氙气、甲烷、乙烯、丙烯、丙烷、氢气、氮气、氟气、氯气、氧气、一氧化二氮(笑气)、二氧化碳、一氧化氮、一氧化碳、二氧化硫和二氯二氟甲烷各自的声速。此外,根据我们得出的公式,我们求出了每种碳氢化合物在其临界温度的十分之九时甲烷、乙烯、丙烯和丙烷中的声速。我们表明,我们在这项工作中推导的简单公式是可靠的,并且与其他研究和文献中获得的结果一致。我们相信它可用于许多低密度且由 Lennard-Jones 势描述的系统。

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