Otto Diels Institute of Organic Chemistry, Christian-Albrechts-Universität zu Kiel, Otto-Hahn-Platz 4, Kiel, 24098, Germany.
Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, OX1 3TA, United Kingdom.
Chempluschem. 2020 Aug;85(8):1824-1841. doi: 10.1002/cplu.202000484.
Ion-pair recognition has emerged from cation and anion recognition and become a diverse and active field in its own right. The last decade has seen significant advances in receptor design in terms of the types of binding motifs, understanding of cooperativity and increase in complexity from heteroditopic to multitopic receptors. As a result, attention has turned to applying this knowledge to the rational design of ion-pair receptors for applications in salt solubilisation and extraction, membrane transport and sensing. This Review highlights recent progress and developments in the design and applications of heteroditopic and multitopic receptors for ion-pair recognition.
离子对识别已经从阳离子和阴离子识别中脱颖而出，成为一个独立的、多样化的活跃领域。在过去的十年中，受体设计在结合基序的类型、协同作用的理解以及从杂双位点受体到多位点受体的复杂性增加方面都取得了重大进展。因此，人们开始关注将这些知识应用于离子对受体的合理设计，以应用于盐增溶和萃取、膜传输和传感等领域。本文综述了近年来杂双位点和多位点受体在离子对识别方面的设计和应用方面的最新进展。
