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基于平行裂纹的用于高灵敏度透明应变传感器的超声图案化银纳米线-丙烯酸酯复合材料

Ultrasonically Patterning Silver Nanowire-Acrylate Composite for Highly Sensitive and Transparent Strain Sensors Based on Parallel Cracks.

作者信息

Liu Gui-Shi, Yang Fan, Xu Jiazhe, Kong Yifei, Zheng Huajian, Chen Lei, Chen Yaofei, Wu Mei X, Yang Bo-Ru, Luo Yunhan, Chen Zhe

机构信息

Key Laboratory of Optoelectronic Information and Sensing Technologies of Guangdong Higher Education Institutes, Guangdong Provincial Key Laboratory of Optical Fiber Sensing and Communications, Jinan University, Guangzhou 510632, China.

State Key Laboratory of Optoelectronic Materials and Technologies, School of Electronics and Information Technology, Sun Yat-Sen University, Guangzhou 510006, China.

出版信息

ACS Appl Mater Interfaces. 2020 Oct 21;12(42):47729-47738. doi: 10.1021/acsami.0c11815. Epub 2020 Oct 6.

Abstract

It has long been a challenge to develop strain sensors with large gauge factor (GF) and high transparency for a broad strain range, to which field silver nanowires (AgNWs) have recently been applied. A dense nanowire (NW) network benefits achieving large stretchability, while a sparse NW network favors realizing high transparency and sensitive response to small strains. Herein, a patterned AgNW-acrylate composite-based strain sensor is developed to circumvent the above trade-off issue via a novel ultrasonication-based patterning technique, where a water-soluble, UV-curable acrylate composite was blended with AgNWs as both a tackifier and a photoresist for finely patterning dense AgNWs to achieve high transparency, while maintaining good stretchability. Moreover, the UV-cured AgNW-acrylate patterns are brittle and capable of forming parallel cracks which effectively evade the Poisson effect and thus increase the GF by more than 200-fold compared to that of the bulk AgNW film-based strain sensor. As a result, the AgNW-based strain sensor possesses a GF of ∼10,486 at a large strain (8%), a high transparency of 90.3%, and a maximum stretchability of 20% strain. The precise monitoring of human radial pulse and throat movements proves the great potential of this sensor as a measurement module for wearable healthcare systems.

摘要

长期以来,开发具有大应变系数(GF)且在宽应变范围内具有高透明度的应变传感器一直是一项挑战,银纳米线(AgNWs)最近已应用于该领域。致密的纳米线(NW)网络有利于实现大拉伸性,而稀疏的NW网络则有利于实现高透明度和对小应变的敏感响应。在此,通过一种基于超声处理的新型图案化技术,开发了一种基于图案化AgNW-丙烯酸酯复合材料的应变传感器,以规避上述权衡问题,其中将水溶性、紫外光固化的丙烯酸酯复合材料与AgNWs混合,作为增粘剂和光刻胶,用于对致密的AgNWs进行精细图案化,以实现高透明度,同时保持良好的拉伸性。此外,紫外光固化的AgNW-丙烯酸酯图案很脆,能够形成平行裂纹,有效规避泊松效应,因此与基于块状AgNW薄膜的应变传感器相比,应变系数增加了200多倍。结果,基于AgNW的应变传感器在大应变(8%)下具有约10486的应变系数、90.3%的高透明度和20%应变的最大拉伸性。对人体桡动脉脉搏和喉咙运动的精确监测证明了这种传感器作为可穿戴医疗系统测量模块的巨大潜力。

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