Zhou Wei, Tian Wenxiang, Qi Tianqi, Liu Shuhua, Feng Chuqiao, Ma Gang, Chang Xiaolin
State Key Laboratory of Water Resources and Hydropower Engineering Science, Wuhan University, Wuhan 430072, China.
Guizhou Survey/Design Research Institute for Water Resources and Hydropower, Guiyang 550002, China.
Materials (Basel). 2020 Oct 1;13(19):4387. doi: 10.3390/ma13194387.
The composited cementitious materials usually have superior performance; for example, using limestone powder (LP) and fly ash (FA) as the admixtures of cement in concrete/mortar is a popular way of improving the properties of concrete/mortar structures. In this work, we performed experimental tests to study the hydration process and pore distribution in mortar containing different ratios of LP and FA. Based on the results of mercury intrusion porosimetry (MIP), a numerical mortar model with random pore is built. The model can reflect the synergistic hydration interaction and filling effect caused by the admixtures of LP and FA. After analyzing the hydration process, the coupled chemical-thermal-mechanical method was used to simulate the characteristics of mortar containing LP and FA. The coupling model can simulate the "hump-type" hydration acceleration stage of the mortar at early age, which is specifically caused by the LP, proved in the experimental test. Additionally, the special, "hump-type" stage is important to enhance the early strength of the mortar. At different levels of admixture content, the random pore model and coupled method can predict the evolution process of the mechanical properties well, at early age and for long-term strength. Both experimental and numerical results suggest that the mortar containing admixtures of the proper ratio of LP to FA have good mechanical properties, which can be applied to engineering structures.
复合胶凝材料通常具有优异的性能;例如,在混凝土/砂浆中使用石灰石粉(LP)和粉煤灰(FA)作为水泥的掺合料是改善混凝土/砂浆结构性能的常用方法。在本研究中,我们进行了试验测试,以研究含不同比例LP和FA的砂浆的水化过程和孔隙分布。基于压汞法(MIP)的结果,建立了具有随机孔隙的数值砂浆模型。该模型能够反映LP和FA掺合料引起的协同水化作用和填充效应。在分析水化过程后,采用化学-热-力学耦合方法模拟含LP和FA的砂浆的特性。耦合模型能够模拟砂浆在早期的“驼峰型”水化加速阶段,试验测试证明这一阶段是由LP引起的。此外,这个特殊的“驼峰型”阶段对于提高砂浆的早期强度很重要。在不同掺合料含量水平下,随机孔隙模型和耦合方法能够很好地预测砂浆在早期和长期强度下力学性能的演变过程。试验和数值结果均表明,含适当比例LP和FA掺合料的砂浆具有良好的力学性能,可应用于工程结构。