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从黄蝉(Tecoma stans(L.))的不同提取物(花、树皮、叶)中生物合成 MgO 纳米粒子及其在处理选定的有机染料中的应用。

Biogenic synthesis of MgO nanoparticles from different extracts (flower, bark, leaf) of Tecoma stans (L.) and their utilization in selected organic dyes treatment.

机构信息

NTT Hi-Tech Institute, Nguyen Tat Thanh University, 300A Nguyen Tat Thanh, District 4, Ho Chi Minh City 755414, Vietnam; Center of Excellence for Green Energy and Environmental Nanomaterials (CE@GrEEN), Nguyen Tat Thanh University, 300A Nguyen Tat Thanh, District 4, Ho Chi Minh City 755414, Vietnam.

Department of Chemical Engineering and Processing, Nong Lam University, Thu Duc District, Ho Chi Minh City 700000, Vietnam.

出版信息

J Hazard Mater. 2021 Feb 15;404(Pt A):124146. doi: 10.1016/j.jhazmat.2020.124146. Epub 2020 Sep 30.

Abstract

The occurrence and influence of dyes-containing effluents are alarmingly serious; hence, the treatment of such wastewater needs to be undertaken. Here, we report the biosynthesis strategy and utilisation of MgO nanoparticles (MgO NPs) from distinct Tecoma stans (L.) plant extracts (flower, bark, and leaf). The FT-IR spectroscopy revealed the dominance of chemical bonds as well as functional groups on MgO NPs surfaces. For adsorption experiments, the impact of pH, contact time, concentration, and pH on uptake efficiency of congo red (CR) and crystal violet (CV) dyes were investigated and then optimized using response surface methodology and Box-Behnken design. Under the optimal conditions, 99.7% CR (at C = 9.33 mg/L, Dos = 0.22, pH = 7.9) and 90.8% CV (at C = 5.0 mg/L, Dos = 0.3, pH = 6.3) were attained. The maximum adsorption capacities were calculated from 89.24 to 150.49 mg/g, where MgO NPs derived from flower extract gave better adsorption efficiency than those from other extracts. Therefore, MgO NPs material from Tecoma stans (L.) flower extract is expected as a perspective adsorbent for the effective remediation of organic dyes.

摘要

染料废水的产生和影响严重,因此需要对这类废水进行处理。在这里,我们报告了从不同的黄蝉(Tecoma stans(L.))植物提取物(花、树皮和叶)合成氧化镁纳米粒子(MgO NPs)的策略及其应用。傅里叶变换红外光谱(FT-IR)揭示了 MgO NPs 表面化学键和官能团的主导地位。在吸附实验中,研究了 pH 值、接触时间、浓度以及 pH 值对刚果红(CR)和结晶紫(CV)染料吸附效率的影响,并采用响应面法和 Box-Behnken 设计进行了优化。在最佳条件下,CR(C = 9.33 mg/L,Dos = 0.22,pH = 7.9)和 CV(C = 5.0 mg/L,Dos = 0.3,pH = 6.3)的去除率分别达到 99.7%和 90.8%。从 89.24 到 150.49 mg/g 计算出最大吸附容量,其中来自花提取物的 MgO NPs 具有比其他提取物更好的吸附效率。因此,来自黄蝉(Tecoma stans(L.))花提取物的 MgO NPs 材料有望成为有效去除有机染料的新型吸附剂。

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