Yang Jingying, Wang Yabin, Pan Mingfei, Xie Xiaoqian, Liu Kaixin, Hong Liping, Wang Shuo
State Key Laboratory of Food Nutrition and Safety, Tianjin University of Science & Technology, Tianjin 300457, China.
Key Laboratory of Food Nutrition and Safety, Ministry of Education of China, Tianjin University of Science and Technology, Tianjin 300457, China.
Foods. 2020 Nov 6;9(11):1610. doi: 10.3390/foods9111610.
A variety of contaminants in food is an important aspect affecting food safety. Due to the presence of its trace amounts and the complexity of food matrix, it is very difficult to effectively separate and accurately detect them. The magnetic metal-organic framework (MMOF) composites with different structures and functions provide a new choice for the purification of food matrix and enrichment of trace targets, thus providing a new direction for the development of new technologies in food safety detection with high sensitivity and efficiency. The MOF materials composed of inorganic subunits and organic ligands have the advantages of regular pore structure, large specific surface area and good stability, which have been thoroughly studied in the pretreatment of complex food samples. MMOF materials combined different MOF materials with various magnetic nanoparticles, adding magnetic characteristics to the advantages of MOF materials, which are in terms of material selectivity, biocompatibility, easy operation and repeatability. Combined with solid phase extraction (SPE) technique, MMOF materials have been widely used in the food pretreatment. This article introduced the new preparation strategies of different MMOF materials, systematically summarizes their applications as SPE adsorbents in the pretreatment of food contaminants and analyzes and prospects their future application prospects and development directions.
食品中的多种污染物是影响食品安全的一个重要方面。由于其含量微量且食品基质复杂,很难对其进行有效分离和准确检测。具有不同结构和功能的磁性金属有机框架(MMOF)复合材料为食品基质的净化和痕量目标物的富集提供了新的选择,从而为高灵敏度和高效率的食品安全检测新技术的发展提供了新方向。由无机亚基和有机配体组成的金属有机框架(MOF)材料具有孔结构规整、比表面积大、稳定性好等优点,在复杂食品样品的预处理方面已有深入研究。MMOF材料将不同的MOF材料与各种磁性纳米粒子相结合,在MOF材料优点的基础上增加了磁性特性,在材料选择性、生物相容性、操作简便性和可重复性方面表现出色。结合固相萃取(SPE)技术,MMOF材料已广泛应用于食品预处理。本文介绍了不同MMOF材料的新制备策略,系统总结了它们作为SPE吸附剂在食品污染物预处理中的应用,并对其未来的应用前景和发展方向进行了分析和展望。