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简单一锅法绿色合成的氧化铜和 CuO@APTES 纳米粒子在豇豆种子纳种中的创新应用。

Innovative application of facile single pot green synthesized CuO and CuO@APTES nanoparticles in nanopriming of Vigna radiata seeds.

机构信息

Nano-bioconjugate Chemistry Lab, Cluster Innovation Centre, Delhi, India.

Department of Environmental Studies, University of Delhi, Delhi, India.

出版信息

Environ Sci Pollut Res Int. 2021 Mar;28(11):13221-13228. doi: 10.1007/s11356-020-11493-6. Epub 2020 Nov 11.

Abstract

Nanopriming is an emerging field of science which uses nanoparticles in solution to improve parameters of seed vigor. This leads to an initial advantage to the crop plant at the germination phase of its life cycle, which is also the most vulnerable phase and may lead to an improved yield. In this study, we have synthesized copper oxide (CuO) and (3-Aminopropyl) triethoxysilane (APTES)-coated CuO (CuO@APTES) nanoparticles via environmentally friendly green synthesis using the extract of Coriandrum sativum (coriander) herb. The synthesized nanoparticles were used as nanoprimers on Vigna radiata (moong bean), a model legume, to promote seed vigor via increase in germination. This was followed by characterization and comparison of both types of nanoparticles using various physicochemical techniques; UV-Visible (UV-Vis), Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), dynamic light scattering (DLS), zeta potential, and transmission electron microscopy (TEM). All characterization techniques pointed out to the successful synthesis and coating of CuO nanoparticles. Seed imbibition and germination assays were performed, which indicated increased imbibition potential and germination promotion at low nanoparticle concentration. Such studies can be used in the development of simple prepackaged nanoprimer products, which can be used by farmers before sowing to provide a boost to their crops and productivity.

摘要

纳米引发是一个新兴的科学领域,它利用溶液中的纳米粒子来改善种子活力的参数。这使得作物在其生命周期的萌发阶段获得了一个初始优势,而萌发阶段也是最脆弱的阶段,可能会导致产量提高。在这项研究中,我们使用芫荽(香菜)草的提取物通过环保的绿色合成方法合成了氧化铜 (CuO) 和 (3-氨丙基) 三乙氧基硅烷 (APTES) 包覆的 CuO (CuO@APTES) 纳米粒子。将合成的纳米粒子用作豇豆(绿豆)的纳米引发剂,通过提高萌发来促进种子活力。随后,使用各种物理化学技术对这两种纳米粒子进行了表征和比较;紫外-可见(UV-Vis)、傅里叶变换红外(FT-IR)光谱、X 射线衍射(XRD)、动态光散射(DLS)、zeta 电位和透射电子显微镜(TEM)。所有的表征技术都表明成功合成并包覆了 CuO 纳米粒子。进行了种子吸胀和萌发实验,结果表明在低纳米粒子浓度下,吸胀潜力增加和萌发促进。这样的研究可以用于开发简单的预包装纳米引发剂产品,农民可以在播种前使用这些产品,为他们的作物和生产力提供助力。

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