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硼-配体协同作用：概念与应用

Boron-Ligand Cooperation: The Concept and Applications.

作者信息

Hasenbeck Max, Gellrich Urs

机构信息

Institut für Organische Chemie, Justus-Liebig-Universität Gießen, Heinrich-Buff-Ring-17, 35392, Gießen, Germany.

出版信息

Chemistry. 2021 Mar 26;27(18):5615-5626. doi: 10.1002/chem.202004563. Epub 2021 Jan 28.

DOI:10.1002/chem.202004563
PMID:33296107
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8048523/
Abstract

The term boron-ligand cooperation was introduced to describe a specific mode of action by which certain metal-free systems activate chemical bonds. The main characteristic of this mode of action is that one covalently bound substituent at the boron is actively involved in the bond activation process and changes to a datively bound ligand in the course of the bond activation. Within this review, how the term boron-ligand cooperation evolved is reflected on and examples of bond activation by boron-ligand cooperation are discussed. It is furthermore shown that systems that operate via boron-ligand cooperation can complement the reactivity of classic intramolecular frustrated Lewis pairs and applications of this new concept for metal-free catalysis are summarized.

摘要

术语“硼-配体协同作用”被引入用于描述某些无金属体系激活化学键的特定作用模式。这种作用模式的主要特征是硼上一个共价键合的取代基积极参与键激活过程，并在键激活过程中转变为配位键合的配体。在这篇综述中，我们思考了“硼-配体协同作用”这一术语是如何演变的，并讨论了通过硼-配体协同作用实现键激活的例子。此外，还表明通过硼-配体协同作用运行的体系可以补充经典分子内受阻路易斯酸碱对的反应性，并总结了这一新概念在无金属催化中的应用。

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