Hao Shuhua, Zhao Xinpei, Cheng Qiyang, Xing Yupeng, Ma Wenxuan, Wang Xiaoke, Zhao Gang, Xu Xijin
Laboratory of Functional Micro and Nano Materials and Devices, School of Physics and Technology, University of Jinan, Jinan, China.
Department of Chemical Engineering and Safety, Binzhou University, Binzhou, China.
Front Chem. 2020 Dec 9;8:582146. doi: 10.3389/fchem.2020.582146. eCollection 2020.
The successful preparation and application of graphene shows that it is feasible for the materials with a thickness of a single atom or few atomic layers to exist stably in nature. These materials can exhibit unusual physical and chemical properties due to their special dimension effects. At present, researchers have made great achievements in the preparation, characterization, modification, and theoretical research of 2D materials. Because the structure of 2D materials is often similar, it has a certain degree of qualitative versatility. Besides, 2D materials often carry good catalytic performance on account of their more active sites and adjustable harmonic electronic structure. In this review, taking 2D materials as examples [graphene, boron nitride (h-BN), transition metal sulfide and so on], we review the crystal structure and preparation methods of these materials in recent years, focus on their photocatalyst properties (carbon dioxide reduction and hydrogen production), and discuss their applications and development prospects in the future.
石墨烯的成功制备与应用表明,单原子层或少数原子层厚度的材料在自然界中稳定存在是可行的。由于其特殊的尺寸效应,这些材料可展现出异常的物理和化学性质。目前,研究人员在二维材料的制备、表征、改性及理论研究方面取得了重大成果。因为二维材料的结构通常相似,所以具有一定程度的定性通用性。此外,二维材料因其具有更多的活性位点和可调节的谐波电子结构,常常具有良好的催化性能。在本综述中,以二维材料(如石墨烯、氮化硼(h-BN)、过渡金属硫化物等)为例,我们回顾了近年来这些材料的晶体结构和制备方法,重点关注它们的光催化剂性能(二氧化碳还原和产氢),并讨论它们未来的应用和发展前景。