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用于减少钛在口腔生物膜中腐蚀的新型涂层

Novel Coatings to Minimize Corrosion of Titanium in Oral Biofilm.

作者信息

Camargo Samira Esteves Afonso, Roy Tanaya, Xia Xinyi, Fares Chaker, Hsu Shu-Min, Ren Fan, Clark Arthur E, Neal Dan, Esquivel-Upshaw Josephine F

机构信息

Department of Restorative Dental Sciences, Division of Prosthodontics, University of Florida College of Dentistry, Gainesville, FL 32610, USA.

Department of Materials Science Engineering, Herbert Wertheim College of Engineering, University of Florida, Gainesville, FL 32611, USA.

出版信息

Materials (Basel). 2021 Jan 12;14(2):342. doi: 10.3390/ma14020342.

Abstract

The aim of this work is to investigate the effects produced by polymicrobial biofilm (, , , and ) on the corrosion behavior of titanium dental implants. Pure titanium disks were polished and coated with titanium nitride (TiN) and silicon carbide (SiC) along with their quarternized versions. Next, the disks were cultivated in culture medium (BHI) with , , , and and incubated anaerobically at 37 °C for 30 days. Titanium corrosion was evaluated through surface observation using Scanning Electron Microscope (SEM) and Atomic Force Microscopy (AFM). Furthermore, the Ti release in the medium was evaluated by Inductively Coupled Plasma Mass Spectrometry (ICP-MS). SEM images showed that coated Ti disks exhibited lower corrosion compared to non-coated disks, except for the quartenized TiN. This was confirmed by AFM, where the roughness was higher in non-coated Ti disks. ICP showed that Ti levels were low in all coating disks. These results indicate that these SiC and TiN-based coatings could be a useful tool to reduce surface corrosion on titanium implant surfaces.

摘要

这项工作的目的是研究多微生物生物膜(、、和)对钛牙科植入物腐蚀行为产生的影响。将纯钛圆盘抛光,并涂覆氮化钛(TiN)和碳化硅(SiC)及其季铵化版本。接下来,将圆盘在含有、、和的培养基(BHI)中培养,并在37℃下厌氧孵育30天。通过使用扫描电子显微镜(SEM)和原子力显微镜(AFM)进行表面观察来评估钛的腐蚀情况。此外,通过电感耦合等离子体质谱法(ICP-MS)评估培养基中钛的释放情况。SEM图像显示,与未涂覆的圆盘相比,涂覆的钛圆盘表现出更低的腐蚀情况,但季铵化TiN除外。原子力显微镜证实了这一点,未涂覆的钛圆盘粗糙度更高。电感耦合等离子体质谱显示所有涂覆圆盘的钛含量都很低。这些结果表明,这些基于SiC和TiN的涂层可能是减少钛植入物表面腐蚀的有用工具。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3cfd/7827847/97703b10c901/materials-14-00342-g001.jpg

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