基于瓜尔豆胶的水凝胶作为可控微量营养素递送系统:农业应用中硼释放的机制和动力学
Guar gum based hydrogel as controlled micronutrient delivery system: Mechanism and kinetics of boron release for agricultural applications.
作者信息
Thombare Nandkishore, Mishra Sumit, Shinde Reshma, Siddiqui M Z, Jha Usha
机构信息
Processing and Product Development Division, ICAR-Indian Institute of Natural Resins and Gums, Ranchi, India.
Department of Chemistry, Birla Institute of Technology, Ranchi, India.
出版信息
Biopolymers. 2021 Mar;112(3):e23418. doi: 10.1002/bip.23418. Epub 2021 Jan 22.
A boron loaded super-absorbent hydrogel (BLSAH) was developed through in situ incorporation of boron (B) in a guar gum-based hydrogel and characterized with FTIR, thermo-gravimetric analysis (TGA), scanning electron microscopy (SEM), and swelling studies, showing maximum absorption up to 356 g/g. The release pattern of B from the BLSAH and its kinetics was studied in water as well as soil. The B release pattern of the BLSAH was also compared with the commercial B fertilizer, boronated single super phosphate (bSSP). The BLSAH, following the Fickian mechanism, released 38% B, as compared with 51% of the bSSP, during the incubation period of 30 days in soil. The half-life period for the BLSAH (96.25 days) in soil was almost triple that of the bSSP's half-life (33.32 days), which is indicative of the slow and controlled release of B from the BLSAH. Thus, owing to its sustained nutrient release ability, the synthesized BLSAH exhibited wide potential for applications in agriculture sector.
通过在瓜尔胶基水凝胶中原位掺入硼(B)制备了一种负载硼的高吸水性水凝胶(BLSAH),并采用傅里叶变换红外光谱(FTIR)、热重分析(TGA)、扫描电子显微镜(SEM)和溶胀研究对其进行了表征,结果表明其最大吸水量可达356 g/g。研究了BLSAH中硼在水和土壤中的释放模式及其动力学。还将BLSAH的硼释放模式与商业硼肥硼化过磷酸钙(bSSP)进行了比较。在土壤中30天的培养期内,遵循菲克扩散机制的BLSAH释放了38%的硼,而bSSP释放了51%的硼。BLSAH在土壤中的半衰期(96.25天)几乎是bSSP半衰期(33.32天)的三倍,这表明BLSAH中硼的释放缓慢且可控。因此,由于其持续的养分释放能力,合成的BLSAH在农业领域具有广泛的应用潜力。