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废水中抗生素的降解：空化处理的新进展

Degradation of Antibiotics in Wastewater: New Advances in Cavitational Treatments.

作者信息

Calcio Gaudino Emanuela, Canova Erica, Liu Pengyun, Wu Zhilin, Cravotto Giancarlo

机构信息

Dipartimento di Scienza e Tecnologia del Farmaco, University of Turin, Via P. Giuria 9, 10125 Turin, Italy.

Huvepharma Italia Srl, Via Roberto Lepetit, 142, 12075 Garessio (CN), Italy.

出版信息

Molecules. 2021 Jan 25;26(3):617. doi: 10.3390/molecules26030617.

DOI:10.3390/molecules26030617
PMID:33504036
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7865544/
Abstract

Over the past few decades, antibiotics have been considered emerging pollutants due to their persistence in aquatic ecosystems. Even at low concentrations, these pollutants contribute to the phenomenon of antibiotic resistance, while their degradation is still a longstanding challenge for wastewater treatment. In the present literature survey, we review the recent advances in synergistic techniques for antibiotic degradation in wastewater that combine either ultrasound (US) or hydrodynamic cavitation (HC) and oxidative, photo-catalytic, and enzymatic strategies. The degradation of sulfadiazine by HC/persulfate (PS)/HO/α-FeO, US/PS/Fe, and sono-photocatalysis with MgO@CNT nanocomposites processes; the degradation of tetracycline by US/HO/FeO, US/O/goethite, and HC/photocatalysis with TiO (P25) sono-photocatalysis with rGO/CdWO protocols; and the degradation of amoxicillin by US/Oxone/Co are discussed. In general, a higher efficiency of antibiotics removal and a faster structure degradation rate are reported under US or HC conditions as compared with the corresponding silent conditions. However, the removal of ciprofloxacin hydrochloride reached only 51% with US-assisted laccase-catalysis, though it was higher than those using US or enzymatic treatment alone. Moreover, a COD removal higher than 85% in several effluents of the pharmaceutical industry (500-7500 mg/L COD) was achieved by the US/O/CuO process.

摘要

在过去几十年中，抗生素因其在水生生态系统中的持久性而被视为新兴污染物。即使在低浓度下，这些污染物也会导致抗生素耐药性现象，而其降解仍是废水处理中一个长期存在的挑战。在本次文献综述中，我们回顾了废水抗生素降解协同技术的最新进展，这些技术结合了超声（US）或水力空化（HC）与氧化、光催化和酶促策略。讨论了HC/过硫酸盐（PS）/HO/α-FeO、US/PS/Fe以及MgO@CNT纳米复合材料的声光催化过程对磺胺嘧啶的降解；US/HO/FeO、US/O/针铁矿以及TiO（P25）的HC/光催化、rGO/CdWO方案的声光催化对四环素的降解；以及US/Oxone/Co对阿莫西林的降解。一般来说，与相应的无声条件相比，在US或HC条件下抗生素去除效率更高，结构降解速率更快。然而，US辅助漆酶催化去除盐酸环丙沙星的效率仅为51%，尽管高于单独使用US或酶处理的效率。此外，US/O/CuO工艺在制药行业的几种废水（化学需氧量为500-7500 mg/L）中实现了高于85%的化学需氧量去除率。

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