铜介导的通过碘三唑将炔烃转化为腈。
Copper-Mediated Conversion of Alkynes into Nitriles via Iodotriazoles.
机构信息
Graduate School of Pharmaceutical Sciences, Nagoya University.
出版信息
Chem Pharm Bull (Tokyo). 2021;69(3):278-280. doi: 10.1248/cpb.c20-00787.
PMID:33642476
Abstract
We disclose our studies on a copper-mediated reaction of alkynes with trimethylsilyl azide to afford nitriles, and proposed a reaction mechanism, which involves an iodoalkyne and an iodotriazole as intermediates.
摘要
我们公开了我们关于炔烃与三甲基硅基叠氮化物的铜介导反应以生成腈的研究，并提出了一种反应机制，其中涉及碘代炔烃和碘代三唑作为中间体。
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