Department of Chemistry, Visva-Bharati (A Central University), Santiniketan 731235, India.
Org Biomol Chem. 2021 Mar 21;19(11):2399-2415. doi: 10.1039/d1ob00082a. Epub 2021 Mar 2.
Visible-light-driven functionalization of various organic systems has proved to be extremely successful and reached an impressive level of sophistication as well as efficiency in the last two decades. At the same time, organosilicon compounds are significant due to their promising applications in therapeutic agents, drug delivery, building blocks and so on. More interestingly, they are cheap, operationally simple, highly stable, less toxic and easy to handle. In this scenario, an environment-friendly synthetic approach for silylation, such as visible-light-induced silylation, is in high demand at present for molecule construction having the C-Si bond. This perspective summarizes the recent findings and developments in the emerging area of photocatalytic silylation with literature coverage mainly extending from 2014 to February 2021.
在过去的二十年中，可见光驱动的各种有机体系的功能化已被证明是非常成功的，并达到了令人印象深刻的复杂程度和效率。与此同时，由于其在治疗剂、药物传递、构建块等方面的应用前景广阔，有机硅化合物也非常重要。更有趣的是，它们廉价、操作简单、高度稳定、毒性低且易于处理。在这种情况下，目前对于构建具有 C-Si 键的分子，人们对环境友好的硅烷化合成方法（如可见光诱导的硅烷化）的需求很高。本综述主要总结了 2014 年至 2021 年 2 月期间光催化硅烷化这一新兴领域的最新发现和进展。
