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通过高压催化氢化合成转变温度高达262K的钇超氢化物超导体。

Synthesis of Yttrium Superhydride Superconductor with a Transition Temperature up to 262 K by Catalytic Hydrogenation at High Pressures.

作者信息

Snider Elliot, Dasenbrock-Gammon Nathan, McBride Raymond, Wang Xiaoyu, Meyers Noah, Lawler Keith V, Zurek Eva, Salamat Ashkan, Dias Ranga P

机构信息

Department of Mechanical Engineering, School of Engineering and Applied Sciences, University of Rochester, Rochester, New York 14627, USA.

Department of Physics and Astronomy, University of Rochester, Rochester, New York 14627, USA.

出版信息

Phys Rev Lett. 2021 Mar 19;126(11):117003. doi: 10.1103/PhysRevLett.126.117003.

Abstract

The recent observation of room-temperature superconductivity will undoubtedly lead to a surge in the discovery of new, dense, hydrogen-rich materials. The rare earth metal superhydrides are predicted to have very high-T_{c} superconductivity that is tunable with changes in stoichiometry or doping. Here we report the synthesis of an yttrium superhydride that exhibits superconductivity at a critical temperature of 262 K at 182±8  GPa. A palladium thin film assists the synthesis by protecting the sputtered yttrium from oxidation and promoting subsequent hydrogenation. Phonon-mediated superconductivity is established by the observation of zero resistance, an isotope effect and the reduction of T_{c} under an external magnetic field. The upper critical magnetic field is 103 T at zero temperature.

摘要

近期对室温超导性的观测无疑将引发新的、致密的富氢材料发现热潮。稀土金属超氢化物预计具有非常高的转变温度((T_{c}))超导性,且该超导性可通过化学计量比或掺杂的变化进行调节。在此,我们报告了一种氢化钇的合成,该氢化钇在182±8吉帕的压力下,于262 K的临界温度下表现出超导性。钯薄膜通过保护溅射的钇不被氧化并促进后续氢化来辅助合成。通过零电阻、同位素效应以及外部磁场下(T_{c})的降低等观测结果,证实了声子介导的超导性。零温度下的上临界磁场为103特斯拉。

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