通过环糊精开环反应一锅法合成不对称二官能化寡麦芽糖苷。
One-Pot Synthesis of Asymmetrically Difunctionalized Oligomaltosides by Cyclodextrin Ring Opening.
机构信息
Laboratoire de Glycochimie, des Antimicrobiens et des Agroressources (LG2A), CNRS UMR 7378, Université de Picardie Jules Verne, 33 rue Saint Leu, 80039, Amiens, France.
出版信息
ChemistryOpen. 2021 Apr;10(4):493-496. doi: 10.1002/open.202100079.
Abstract
The synthesis of pure difunctionalized hexa-, hepta- and octamaltosides was performed by one-pot chemical reaction from perbenzoylated cyclodextrin. Oligomaltosides with azide, propargyl or allyl on reducing end and an unprotected hydroxyl group on non-reducing end were obtained from perbenzoylated α-, β- and γ-cyclodextrin with 12 to 48 % yields.
摘要
通过一锅化学法从全乙酰化环糊精合成纯的六、七和八聚麦芽糖。通过全乙酰化的α-、β-和γ-环糊精，以 12 至 48%的产率获得了具有叠氮基、炔丙基或烯丙基的还原性末端和非还原性末端的未保护羟基的寡麦芽糖。
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