Coffee Consulate, Hans-Thoma-Strasse 20, 68163 Mannheim, Germany.
Yeast Genetics and Fermentation Technology, Institute of Food Science and Biotechnology, University of Hohenheim, Garbenstrasse 23, 70599 Stuttgart, Germany.
Molecules. 2021 Apr 28;26(9):2585. doi: 10.3390/molecules26092585.
Methanol is a natural ingredient with major occurrence in fruit spirits, such as apple, pear, plum or cherry spirits, but also in spirits made from coffee pulp. The compound is formed during fermentation and the following mash storage by enzymatic hydrolysis of naturally present pectins. Methanol is toxic above certain threshold levels and legal limits have been set in most jurisdictions. Therefore, the methanol content needs to be mitigated and its level must be controlled. This article will review the several factors that influence the methanol content including the pH value of the mash, the addition of various yeast and enzyme preparations, fermentation temperature, mash storage, and most importantly the raw material quality and hygiene. From all these mitigation possibilities, lowering the pH value and the use of cultured yeasts when mashing fruit substances is already common as best practice today. Also a controlled yeast fermentation at acidic pH facilitates not only reduced methanol formation, but ultimately also leads to quality benefits of the distillate. Special care has to be observed in the case of spirits made from coffee by-products which are prone to spoilage with very high methanol contents reported in past studies.
甲醇是一种天然成分,主要存在于水果烈酒中,如苹果、梨、李子或樱桃烈酒,也存在于用咖啡果肉制成的烈酒中。该化合物是在发酵过程中以及随后的醪液储存过程中通过天然存在的果胶的酶解形成的。甲醇在超过一定阈值水平时是有毒的,大多数司法管辖区都规定了法定限量。因此,需要减轻甲醇的含量,并控制其水平。本文将综述影响甲醇含量的几个因素,包括醪液的 pH 值、各种酵母和酶制剂的添加、发酵温度、醪液储存,以及最重要的是原料质量和卫生。在所有这些减轻影响的可能性中,降低 pH 值和在糖化水果物质时使用培养酵母已经是当今最佳实践的常用方法。在酸性 pH 值下进行受控酵母发酵不仅有助于减少甲醇的形成,而且最终还会对馏出物的质量带来益处。在过去的研究中,用咖啡副产品制成的烈酒容易变质,甲醇含量非常高,因此需要特别注意。