Li Aimin, Xiong Shenglun, Zhou Wei, Zhai Huijuan, Liu Yuanchu, He Qing
State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineer Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, No. 2 South Lushan Road, Yuelu District, Changsha 410082, P. R. China.
Chem Commun (Camb). 2021 May 6;57(37):4496-4499. doi: 10.1039/d1cc01158h.
A new superphane, featuring an aesthetically pleasing structure, was successfully obtained via one-pot synthesis of a hexakis-amine and m-phthalaldehyde in a [2+6] manner. It proved capable of entrapping a water dimer within its cavity as inferred from the mass spectroscopy, crystallographical analysis, NMR spectroscopy, and theoretical calculations.
通过六胺与间苯二甲醛以[2+6]方式一锅法合成，成功获得了一种具有美观结构的新型超环番。从质谱、晶体学分析、核磁共振光谱和理论计算推断，它能够在其腔内捕获一个水二聚体。
