CuSe nanowires shelled with NiFe layered double hydroxide nanosheets for overall water-splitting.

It is imperative but challenging to develop non-noble metal-based bifunctional electrocatalysts for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). Our work reports a core-shell nanostructure that is constructed by the electrodeposition of ultrathin NiFe-LDH nanosheets (NiFe-LDHNS) on CuSe nanowires, which are obtained by selenizing Cu(OH) nanowires in situ grown on Cu foam. The obtained CuSe@NiFe-LDHNS electrocatalyst provides more exposed edges and catalytic active sites, thus exhibiting excellent OER and HER electrocatalytic performance in alkaline electrolytes. This catalyst needs only an overpotential of 197 mV for OER at 50 mA cm and 195 mV for HER at 10 mA cm. Besides, when employed as a bifunctional catalyst for overall water-splitting, it requires a cell voltage of 1.67 V to reach 10 mA cm in alkaline media. Furthermore, the corresponding water electrolyzer demonstrates robust durability for at least 40 h. The excellent performance of CuSe@NiFe-LDHNS might be ascribed to the synergistic effect from the ultrathin NiFe-LDHNS, the CuSe nanowires anchored on the Cu foam, and the formed core-shell nanostructure, which offers large surface area, ample active sites, and sufficient channels for gas and electrolyte diffusion. This work provides an efficient strategy for the fabrication of self-supported electrocatalysts for efficient overall water-splitting.