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微波辅助绿色合成银纳米粒子在光学、催化、生物和电化学方面的应用。

Microwave assisted green synthesis of silver nanoparticles for optical, catalytic, biological and electrochemical applications.

机构信息

Department of Chemistry, St. Joseph's College, Arakulam, India.

Department of Chemistry, Sree Sankara Vidyapeetom College, Valayanchirangara, Irapuram, India.

出版信息

Artif Cells Nanomed Biotechnol. 2021 Dec;49(1):438-449. doi: 10.1080/21691401.2021.1925678.

Abstract

Plant-derived nanoparticles have multi-functionalities owing to their ecological origin and biocompatible nature. A novel and stable silver nanoparticle (AgNP) was reported here using () as a reducing as well as capping agent by rapid microwave-assisted green method. The synthesized nanoparticles revealed their crystalline and spherical nature with an average size of 19.25 ± 0.44 nm in HR-TEM analysis. The excitation of electrons from occupied d-bands to states above the Fermi level while employing photoluminescence studies of AgNP indicated their awesome optical properties. Rapid decomposition of dangerous organic dyes like methylene blue and fuchsine in the catalytic presence of AgNP was evidenced from simple UV-visible spectral analysis antioxidant potential assessed by DPPH assay indicated an IC value of 40.80 ± 0.14 μg/mL for the new AgNP. A substantial control on the growth of pathogenic bacteria such as and can be achieved by synthesized nanoparticles as demonstrated by the well diffusion method. AgNP was also functioned as a non-enzymatic electrochemical sensor with a sharp oxidation peak with peak potentials at 0.366 V and it has a wide application as a bio sensor in neurobiology especially in the detection of neurotransmitters like dopamine with high sensitivity.

摘要

植物来源的纳米粒子具有多功能性,因为它们具有生态起源和生物相容性。本文报道了一种新颖且稳定的银纳米粒子(AgNP),使用()作为还原剂和封端剂,通过快速微波辅助绿色方法合成。合成的纳米粒子在高分辨率透射电子显微镜(HR-TEM)分析中显示出其结晶和球形性质,平均粒径为 19.25±0.44nm。电子从占据的 d 带激发到费米能级以上的状态,而 AgNP 的光致发光研究表明了其出色的光学性质。AgNP 在催化存在下迅速分解危险有机染料,如亚甲蓝和碱性品红,从简单的紫外可见光谱分析中得到证实。通过 DPPH 测定法评估的抗氧化潜力表明,新合成的 AgNP 的 IC 值为 40.80±0.14μg/mL。通过良好的扩散方法,证明合成的纳米粒子可以对病原菌(如 和 )的生长进行有效控制。AgNP 还可以作为非酶电化学传感器发挥作用,具有尖锐的氧化峰,峰电位为 0.366 V,它在神经生物学中的生物传感器中具有广泛的应用,特别是在检测神经递质如多巴胺方面具有高灵敏度。

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