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[离子色谱中使用的电渗析技术进展]

[Advances of electrodialytic technologies used in ion chromatography].

作者信息

Yang Bingcheng, Li Zongying

机构信息

School of Pharmacy, East-China University of Science and Technology, Shanghai 200237, China.

出版信息

Se Pu. 2021 Feb;39(2):130-133. doi: 10.3724/SP.J.1123.2020.07016.

Abstract

An electrodialysis device is used to transport salt ions from one solution to another through an ion-exchange membrane under the influence of an applied electric potential. They can produce hydronium or hydroxide ions via electrodialysis water, which can be used for online preparation of eluents or suppression or detection in ion chromatography (IC). As opposed to the manual preparation of eluents or regenerant solutions, electrodialysis devices have the advantages such as green, efficient and high purity. Thus, IC systems equipped with electrodialysis devices dominate the majority uses of IC system, and more importantly, find widespread application. The present thesis briefly summarizes the latest developments in this area.

摘要

电渗析装置用于在施加的电势影响下,通过离子交换膜将盐离子从一种溶液传输到另一种溶液。它们可以通过电渗析水产生水合氢离子或氢氧根离子,可用于在线制备洗脱液或在离子色谱(IC)中进行抑制或检测。与手动制备洗脱液或再生溶液相比,电渗析装置具有绿色、高效和高纯度等优点。因此,配备电渗析装置的离子色谱系统在离子色谱系统的大多数应用中占主导地位,更重要的是,得到了广泛应用。本论文简要总结了该领域的最新进展。

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本文引用的文献

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Electrodialysis Pump Based on Enhanced Water Dissociation of Bipolar Membrane.基于双极膜增强水离解的电渗析泵。
Anal Chem. 2020 May 5;92(9):6263-6268. doi: 10.1021/acs.analchem.0c01077. Epub 2020 Apr 24.
5
Carbonic Acid Eluent Ion Chromatography.碳酸洗脱离子色谱法。
Anal Chem. 2019 Mar 5;91(5):3636-3644. doi: 10.1021/acs.analchem.8b05627. Epub 2019 Feb 21.
6
Online Gas-Free Electrodialytic KOH Eluent Generator for Ion Chromatography.用于离子色谱的在线无气电解KOH淋洗液发生器
Anal Chem. 2018 Nov 6;90(21):12840-12845. doi: 10.1021/acs.analchem.8b03365. Epub 2018 Oct 12.
8
Electrodialytic in-line preconcentration for ionic solute analysis.电渗析在线预浓缩用于离子溶质分析。
Talanta. 2018 Apr 1;180:176-181. doi: 10.1016/j.talanta.2017.12.054. Epub 2017 Dec 18.

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