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由美人蕉花朵生物合成的多功能氧化锌纳米颗粒用于种子萌发、吸附及有机染料的光催化降解

Multifunctional ZnO nanoparticles bio-fabricated from Canna indica L. flowers for seed germination, adsorption, and photocatalytic degradation of organic dyes.

作者信息

Nguyen Duyen Thi Cam, Le Hanh T N, Nguyen Thuong Thi, Nguyen Thi Thanh Thuy, Bach Long Giang, Nguyen Trinh Duy, Tran Thuan Van

机构信息

Institute of Environmental Sciences, Nguyen Tat Thanh University, 298-300A Nguyen Tat Thanh, District 4, Ho Chi Minh City 755414, Viet Nam; Faculty of Environmental and Food Engineering, Nguyen Tat Thanh University, 298-300A Nguyen Tat Thanh, District 4, Ho Chi Minh City 755414, Viet Nam.

Institute of Hygiene and Public Health, 159 Hung Phu, Ward 8, District 8, Ho Chi Minh City 700000, Viet Nam.

出版信息

J Hazard Mater. 2021 Oct 15;420:126586. doi: 10.1016/j.jhazmat.2021.126586. Epub 2021 Jul 7.

Abstract

The potential of green nanomaterials for environmental and agricultural fields is emerging due to their biocompatible, eco-friendly, and cost-effective performance. We report the use of Canna indica flowers extract as new capping and stabilizing source to bio-fabricate ZnO nanoparticles (ZnO NPs for dyes removal, seed germination. ZnO NPs was biosynthesized by ultrasound-assisted alkaline-free route to reach the critical green strategy. The physicochemical findings of ZnO revealed small crystallite size (27.82 nm), sufficient band-gap energy (3.08 eV), and diverse functional groups. Minimum‑run resolution IV approach found the most pivotal factors influencing on removal of Coomassie Brilliant Blue G-250. Uptake studies pointed out that pseudo second-order, and Langmuir were the best fitted models. Dye molecules behaved monolayer adsorption on ZnO surface layers, and controlled by chemisorption. Natural solar light was used as effective source for photocatalytic degradation of methylene blue (94.23% of removal and 31.09 mg/g of uptake capacity). Compared with HO and ZnSO, ZnO NPs positively affected the growth of shoot and root lengths (10.2-27.8%) of bean seedlings in most cases. ZnO acts an agrochemical for boosting weight gain, and germination ratio. This study may be promising for developing the recyclable, multifunctional ZnO nanoparticles for environmental and agricultural applications.

摘要

由于其具有生物相容性、生态友好性和成本效益,绿色纳米材料在环境和农业领域的潜力正在显现。我们报道了使用美人蕉花提取物作为新的封端和稳定来源,生物制备用于染料去除、种子萌发的氧化锌纳米颗粒(ZnO NPs)。通过超声辅助无碱路线生物合成ZnO NPs以实现关键的绿色策略。ZnO的物理化学研究结果显示出小的微晶尺寸(27.82 nm)、足够的带隙能量(3.08 eV)和多种官能团。最小运行分辨率IV方法发现了影响考马斯亮蓝G-250去除的最关键因素。吸附研究指出,准二级动力学和朗缪尔模型是拟合效果最好的模型。染料分子在ZnO表面层表现为单层吸附,并受化学吸附控制。自然太阳光被用作亚甲基蓝光催化降解的有效光源(去除率94.23%,吸附容量31.09 mg/g)。与过氧化氢和硫酸锌相比,在大多数情况下,ZnO NPs对菜豆幼苗的地上部和根部长度生长有积极影响(10.2 - 27.8%)。ZnO可作为一种农用化学品促进重量增加和发芽率。这项研究对于开发用于环境和农业应用的可回收、多功能氧化锌纳米颗粒可能具有前景。

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