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3D打印和增材制造中增强光聚合反应的协同动力学与策略的批判性综述

A Critical Review for Synergic Kinetics and Strategies for Enhanced Photopolymerizations for 3D-Printing and Additive Manufacturing.

作者信息

Lin Jui-Teng, Lalevee Jacques, Cheng Da-Chun

机构信息

New Vision Inc., 10F, No. 55, Sect.3, Xinbei Blvd, Xinzhuang, New Taipei City 242, Taiwan.

CNRS, IS2M UMR 7361, Université de Haute-Alsace, F-68100 Mulhouse, France.

出版信息

Polymers (Basel). 2021 Jul 15;13(14):2325. doi: 10.3390/polym13142325.

DOI:10.3390/polym13142325
PMID:34301082
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8309579/
Abstract

The synergic features and enhancing strategies for various photopolymerization systems are reviewed by kinetic schemes and the associated measurements. The important topics include (i) photo crosslinking of corneas for the treatment of corneal diseases using UVA-light (365 nm) light and riboflavin as the photosensitizer; (ii) synergic effects by a dual-function enhancer in a three-initiator system; (iii) synergic effects by a three-initiator C/B/A system, with electron-transfer and oxygen-mediated energy-transfer pathways; (iv) copper-complex (G1) photoredox catalyst in G1/Iod/NVK systems for free radical (FRP) and cationic photopolymerization (CP); (v) radical-mediated thiol-ene (TE) photopolymerizations; (vi) superbase photogenerator based-catalyzed thiol-acrylate Michael (TM) addition reaction; and the combined system of TE and TM using dual wavelength; (vii) dual-wavelength (UV and blue) controlled photopolymerization confinement (PC); (viii) dual-wavelength (UV and red) selectively controlled 3D printing; and (ix) three-wavelength selectively controlled in 3D printing and additive manufacturing (AM). With minimum mathematics, we present (for the first time) the synergic features and enhancing strategies for various systems of multi-components, initiators, monomers, and under one-, two-, and three-wavelength light. Therefore, this review provides not only the bridging between modeling and measurements, but also guidance for further experimental studies and new applications in 3D printings and additive manufacturing (AM), based on the innovative concepts (kinetics/schemes).

摘要

通过动力学方案和相关测量，综述了各种光聚合体系的协同特性和增强策略。重要主题包括：（i）使用UVA光（365nm）和核黄素作为光敏剂对角膜进行光交联以治疗角膜疾病；（ii）三引发剂体系中双功能增强剂的协同效应；（iii）具有电子转移和氧介导能量转移途径的三引发剂C/B/A体系的协同效应；（iv）G1/Iod/NVK体系中用于自由基光聚合（FRP）和阳离子光聚合（CP）的铜配合物（G1）光氧化还原催化剂；（v）自由基介导的硫醇-烯（TE）光聚合；（vi）基于超强碱光引发剂催化的硫醇-丙烯酸酯迈克尔（TM）加成反应；以及使用双波长的TE和TM组合体系；（vii）双波长（紫外和蓝光）控制的光聚合限制（PC）；（viii）双波长（紫外和红光）选择性控制的3D打印；以及（ix）3D打印和增材制造（AM）中的三波长选择性控制。我们以最少的数学知识（首次）呈现了多组分、引发剂、单体以及在单波长、双波长和三波长光下各种体系的协同特性和增强策略。因此，本综述不仅在建模和测量之间架起了桥梁，还基于创新概念（动力学/方案）为进一步的实验研究以及3D打印和增材制造（AM）中的新应用提供了指导。

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