Ma Yin, Xiong Lijun, Lu Yao, Zhu Wenqiang, Zhao Haihong, Yang Yahui, Mao Liqiu, Yang Lishan
Key Laboratory of Chemical Biology & Traditional Chinese Medicine Research (Ministry of Education of China), National and Local Joint Engineering Laboratory for New Petrochemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha, China.
Front Chem. 2021 Jul 9;9:638216. doi: 10.3389/fchem.2021.638216. eCollection 2021.
Inorganic nitride nanomaterials have attracted widespread attention for applications in renewable energy due to novel electrochemical activities and high chemical stabilities. For different renewable energy applications, there are many possibilities and uncertainties about the optimal nitride phases and nanostructures, which further promotes the exploration of controllable preparation of nitride nanomaterials. Moreover, unlike conventional nitrides with bulk or ceramic structures, the synthesis of nitride nanomaterials needs more accurate control to guarantee the target nanostructure along with the phase purity, which make the whole synthesis still a challenge to achieve. In this mini review, we mainly summarize the synthesis methods for inorganic nitride nanomaterials, including chemistry vapor deposition, self-propagation high-temperature synthesis, solid state metathesis reactions, solvothermal synthesis, . From the perspective of nanostructure, several novel nitrides, with nanostructures like nanoporous, two-dimensional, defects, ternary structures, and quantum dots, are showing unique properties and getting extensive attentions, recently. Prospects of future research in design and synthesis of functional inorganic nitrides are also discussed.
无机氮化物纳米材料因其新颖的电化学活性和高化学稳定性，在可再生能源应用中受到广泛关注。对于不同的可再生能源应用，关于最佳氮化物相和纳米结构存在许多可能性和不确定性，这进一步推动了对氮化物纳米材料可控制备的探索。此外，与具有块状或陶瓷结构的传统氮化物不同，氮化物纳米材料的合成需要更精确的控制，以确保目标纳米结构以及相纯度，这使得整个合成过程仍然是一个具有挑战性的任务。在本综述中，我们主要总结了无机氮化物纳米材料的合成方法，包括化学气相沉积、自蔓延高温合成、固态复分解反应、溶剂热合成等。从纳米结构的角度来看，几种具有纳米多孔、二维、缺陷、三元结构和量子点等纳米结构的新型氮化物，最近展现出独特的性能并受到广泛关注。本文还讨论了功能性无机氮化物设计与合成未来研究的前景。
