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具有简便高效的自制惰性气氛手套箱选项的多功能、低成本且便携的二维材料转移装置。

Versatile, Low-Cost, and Portable 2D Material Transfer Setup with a Facile and Highly Efficient DIY Inert-Atmosphere Glove Compartment Option.

作者信息

Buapan Kanokwan, Somphonsane Ratchanok, Chiawchan Tinna, Ramamoorthy Harihara

机构信息

Department of Physics, Faculty of Science, King Mongkut's Institute of Technology Ladkrabang, 1 Chalongkrung Road, Bangkok 10520, Thailand.

Thailand Center of Excellence in Physics, Commission on Higher Education, 328 Si Ayutthaya Road, Bangkok 10400, Thailand.

出版信息

ACS Omega. 2021 Jul 7;6(28):17952-17964. doi: 10.1021/acsomega.1c01582. eCollection 2021 Jul 20.

Abstract

Research in van der Waals heterostructures has been rapidly progressing in the past decade, thanks to the art of sequential and deterministic placement of one two-dimensional (2D) material over another. The successful creation of heterostructures however has relied largely on expensive transfer systems that are not easily accessible to researchers. Although a few reports on low-cost systems have recently surfaced, the full functionality, portability features, and overall effectiveness of such systems are still being explored. In this work, we present an "all-in-one" low-cost transfer setup that is compact, lightweight, and portable and which can be quickly installed with a facile and do it yourself (DIY)-style anaerobic glovebox option that performs at par with commercial anaerobic systems. The "installable" glovebox option means the user has the convenience of quickly converting the working environment into an inert one when air-sensitive 2D materials are used. The lowest RH values obtained in our glovebox is <3%, and the O levels rapidly drop from 21% to less than 0.1% in just a few minutes of purging the chamber with inert gas. The transfer system is also equipped with a light-weight PID-controlled substrate heating option that can be easily assembled within just a few hours. We test the versatility of our low-cost system by the successful creation of hexagonal boron nitride (hBN)-encapsulated graphene and hBN-encapsulated molybdenum disulphide (MoS) heterostructures using the hot pickup technique and graphene-hBN, MoS-hBN, twisted MoS, and twisted MoS on hBN stacks using the wetting technique, and a MoS-hBN-graphene vertical tunneling heterostructure was formed using a combination approach. The effectiveness of the DIY glovebox is proven with the demonstration of extended stability of freshly exfoliated black phosphorous (BP) flakes, their encapsulation between thin hBN layers, and the formation of electrically contacted BP devices with a protective hBN top layer. At an overall price point of approximately 1000 $, the versatile setup presented here is expected to further contribute to the growth of research in 2D materials, in particular, for researchers initially faced with overcoming a huge entry-level threshold to work in the field of 2D materials and van der Waals heterostructures.

摘要

在过去十年中,范德华异质结构的研究进展迅速,这得益于将一种二维(2D)材料依次且确定性地放置在另一种材料之上的技术。然而,异质结构的成功制备在很大程度上依赖于昂贵的转移系统,研究人员难以轻易获得。尽管最近有一些关于低成本系统的报道,但此类系统的全部功能、便携性特点以及整体有效性仍在探索之中。在这项工作中,我们展示了一种“一体化”低成本转移装置,它紧凑、轻便且便于携带,并且可以通过一种简便的、自己动手(DIY)式的厌氧手套箱选项快速安装,其性能与商业厌氧系统相当。“可安装”的手套箱选项意味着当使用对空气敏感的二维材料时,用户可以方便地将工作环境快速转换为惰性环境。我们的手套箱中获得的最低相对湿度值小于3%,并且在使用惰性气体吹扫腔室几分钟后,氧气含量从21%迅速降至低于0.1%。该转移系统还配备了一个轻量级的、由比例积分微分(PID)控制的衬底加热选项,只需几个小时就能轻松组装完成。我们通过使用热拾取技术成功制备六方氮化硼(hBN)封装的石墨烯和hBN封装的二硫化钼(MoS)异质结构,以及使用湿化技术在hBN堆叠上制备石墨烯 - hBN、MoS - hBN、扭曲的MoS和扭曲的MoS,并通过组合方法形成MoS - hBN - 石墨烯垂直隧道异质结构,来测试我们低成本系统的多功能性。通过展示新剥离的黑磷(BP)薄片的延长稳定性、它们在薄hBN层之间的封装以及形成具有保护性hBN顶层的电接触BP器件,证明了DIY手套箱的有效性。这里展示的这种多功能装置总体价格约为1000美元,预计将进一步推动二维材料研究的发展,特别是对于那些最初面临巨大入门门槛而难以进入二维材料和范德华异质结构领域工作的研究人员。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e44/8296015/9e8bf932fc3a/ao1c01582_0002.jpg

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