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源自香蕉皮废料的生物质多孔碳作为锂离子电池的可持续阳极

Biomass Porous Carbons Derived from Banana Peel Waste as Sustainable Anodes for Lithium-Ion Batteries.

作者信息

Luna-Lama Fernando, Morales Julián, Caballero Alvaro

机构信息

Departamento Química Inorgánica e Ingeniería Química, Instituto Universitario de Química Fina y Nanoquímica (IUNAN), Facultad de Ciencias, Universidad de Córdoba, 14071 Córdoba, Spain.

出版信息

Materials (Basel). 2021 Oct 12;14(20):5995. doi: 10.3390/ma14205995.

Abstract

Disordered carbons derived from banana peel waste (BPW) were successfully obtained by employing a simple one-step activation/carbonization method. Different instrumental techniques were used to characterize the structural, morphological, and textural properties of the materials, including X-ray diffraction, thermogravimetric analysis, porosimetry and scanning electron microscopy with energy-dispersive X-ray spectroscopy. The chemical activation with different porogens (zinc chloride, potassium hydroxide and phosphoric acid) could be used to develop functional carbonaceous structures with high specific surface areas and significant quantities of pores. The BPW@HPO carbon exhibited a high specific surface area (815 m g), chemical stability and good conductivity for use as an anode in lithium-ion batteries. After 200 cycles, this carbon delivered a reversible capacity of 272 mAh g at 0.2 C, showing a notable retention capacity and good cycling performance even at high current densities, demonstrating its effectiveness and sustainability as an anode material for high-energy applications in Li-ion batteries.

摘要

通过采用简单的一步活化/碳化方法,成功地从香蕉皮废料(BPW)中获得了无序碳。使用了不同的仪器技术来表征材料的结构、形态和纹理特性,包括X射线衍射、热重分析、孔隙率测定以及带有能量色散X射线光谱的扫描电子显微镜。用不同的致孔剂(氯化锌、氢氧化钾和磷酸)进行化学活化,可用于开发具有高比表面积和大量孔隙的功能性碳质结构。BPW@HPO碳表现出高比表面积(815 m²/g)、化学稳定性和良好的导电性,可用作锂离子电池的阳极。经过200次循环后,这种碳在0.2 C下的可逆容量为272 mAh/g,即使在高电流密度下也显示出显著的保留容量和良好的循环性能,证明了其作为锂离子电池高能应用阳极材料的有效性和可持续性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9713/8538914/97135f96f95d/materials-14-05995-sch001.jpg

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