Recent advances in electrospinning supramolecular systems.

Electrospinning is one of the simple, versatile, and convenient techniques for producing nanofibers that have found numerous applications in the fields of biomedical engineering, surface materials, and catalysis. Despite the great achievements, the electrospinning compounds are still limited to the utilization of polymers with high molar mass which are regarded as an indispensable element for the production of nanofibers. It is found that electrospinning chemicals based on supramolecular systems can avoid the use of high molecular weight polymers, and it is emerging as a powerful route to generate fibers in the nano-scale size. The presence of strong intermolecular interactions that function as chain entanglements allows for the formation of nanofibers during the process of electrospinning. This article provides recent impressive developments concerning nanofiber preparation made by the combination of electrospinning and supramolecular chemistry, which enables easy access to tailor-made nanofibers. Electrospinning supramolecular systems consisting of phospholipids, surfactants, crown ether derivatives as well as cyclodextrins will be highlighted in this review. Moreover, we will pay particular attention to the functionalities of electrospun nanofibers obtained from supramolecular systems.