Quantification of sonochemical and sonophysical effects in a 20 kHz probe-type sonoreactor: Enhancing sonophysical effects in heterogeneous systems with milli-sized particles.

Even though acoustic cavitation has been widely investigated, only few researchers focused on the relationship between sonochemical and sonophysical activities and on the enhancement of sonophysical activity. In this study, sonochemical and sonophysical activities were investigated in a heterogeneous system to understand the relationship between these two activities and to suggest optimal conditions for ultrasonic desorption/extraction processes comprising milli-sized glass beads. The sonochemical activity was quantitatively analyzed using potassium iodide dosimetry in homogeneous and heterogeneous systems. Sonophysical activity was quantitatively and qualitatively analyzed using paint-coated bead desorption tests and aluminum foil erosion tests under three probe positions of "T" (1 cm below the liquid surface), "B" (1 cm above the vessel bottom), and "M" (midpoint between "T" and "B"). Three different sizes of glass beads (diameter: 0.2, 1.0, and 4.0 mm) were used in this study. The highest sonochemical activity was obtained at "B" in both homogeneous and heterogeneous systems. However, three times lower sonochemical activity was observed in the heterogeneous system than in the homogeneous system because significant attenuation and unstable reflection of ultrasound occurred in the bead layer and suspension. Higher sonophysical activity was observed, when the bead size decreased and the probe approached the bottom. However, no significant sonophysical activity was detected when the beads were attached to the bottom. Therefore, the sonophysically active region was the zone around the probe body, opposite to the ultrasound irradiation tip, and only suspended beads could undergo severe cavitational actions. This was confirmed via aluminum foil tests. Several erosion marks on the foil were observed in the area around the probe body, whereas no severe damage was observed at the bottom. Moreover, the degree of sonophysical activity did not change for various saturating gases. This might be due to the different thresholds of sonochemical and sonophysical activities.